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MgO對YAG透明陶瓷燒結(jié)性能的影響
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中國科學(xué)院上海硅酸鹽研究所

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TQ174

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上海市自然科學(xué)基金項(xiàng)目


The effect of MgO on the properties of YAG transparent ceramics
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Shanghai Institute of Ceramics, CAS

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    摘要:

    采用真空固相反應(yīng)燒結(jié)技術(shù)制備了YAG透明陶瓷,測試了陶瓷素坯的熱膨脹曲線,陶瓷樣品的透過光譜及表面微結(jié)構(gòu)。深入研究了MgO作為燒結(jié)助劑,其添加量對YAG透明陶瓷顯微結(jié)構(gòu)、光學(xué)透過率等性能的影響。結(jié)果表明,在1780℃下保溫6小時,制備得到具有高透明度的YAG透明陶瓷。0.1 wt.%以上的MgO添加量有利于陶瓷的致密化,但由于第二相的產(chǎn)生及氣孔不能排除,嚴(yán)重降低了陶瓷的光學(xué)質(zhì)量;添加0.03 wt.%的MgO最有利于透明陶瓷的燒結(jié),制備得到的陶瓷晶粒尺寸均一,約為10 μm,幾乎無晶內(nèi)及晶間氣孔,其在1200 nm處的透過率約為82 %。

    Abstract:

    YAG transparent ceramic has been successfully fabricated by the vacuum sintering technique, with MgO as sintering aids. Thermal expansion curves of the green samples, optical transmittance spectrum, and surface microstructure of the prepared YAG ceramics were measured. The effect of MgO content on the microstructure, in-line transmittance of the samples was systematically studied. Transparent ceramics with high optical quality were obtained after vacuum sintered at 1780 ℃ for 6 h. Ceramics with MgO at the level above 0.1 wt.% were easy to densify, however, the second phase and pores appeared then, which did harm for the optical quality of the samples. 0.03 wt.% of MgO content benefited the sintering process most. Uniform grains with about 10μm were gained, with neither inner nor intergranular pores. The in-line transmittace of the ceramic at 1100 nm reached 82%.

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覃顯鵬. MgO對YAG透明陶瓷燒結(jié)性能的影響[J].稀有金屬材料與工程,2016,45(1):240~243.[Qin Xianpeng. The effect of MgO on the properties of YAG transparent ceramics[J]. Rare Metal Materials and Engineering,2016,45(1):240~243.]
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  • 收稿日期:2014-02-19
  • 最后修改日期:2014-03-14
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  • 在線發(fā)布日期: 2019-01-04
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