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W-30Cu納米復(fù)合粉末液相燒結(jié)致密化與晶粒長大機制
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國家杰出青年科學(xué)基金 (50925416);國家自然科學(xué)基金 (50874122)


Densification and Grain Growth Mechanism of Nanosized W-30Cu Powder during Liquid Phase Sintering
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    摘要:

    采用噴霧干燥-煅燒、還原工藝制備超細(xì)W-30Cu復(fù)合粉末,將粉末模壓成形,在1340~1420 ℃液相燒結(jié)15~120 min,研究其致密化行為及晶粒長大機制。結(jié)果表明:W-30Cu復(fù)合粉末在液相燒結(jié)早期發(fā)生了顯著的致密化,1340 ℃燒結(jié)15 min致密度可達(dá)到90%以上;隨燒結(jié)時間的延長致密度增加,1380 ℃燒結(jié)90 min相對密度達(dá)到99.1%。液相燒結(jié)過程中,W晶粒不斷長大并逐漸球化,且其晶粒大小G與燒結(jié)時間t符合 G3∝kt關(guān)系,服從液相燒結(jié)溶解-析出機制。燒結(jié)溫度對W晶粒長大影響顯著,當(dāng)溫度從1340 ℃上升到1420 ℃時,其晶粒長大動力學(xué)系數(shù)從1.61×10?2μm3/min增大到4.65×10?2μm3/min,液相的形成、顆粒重排、溶解-析出及W晶粒長大使細(xì)晶W-Cu獲得近全致密

    Abstract:

    W-30Cu composite powder fabricated by sol-spray drying and subsequent hydrogen reduction was pressed and directly liquid phase sintered at 1340~1420 ℃ for 15~120 min, the densification and grain growth mechanism were studied. The results show that the significant densification occurs in the early sintering stage of the liquid phase. When sintered at 1340 ℃ for 15 min, the relative density reaches above 90%. With the sintering time increases, the relative density increases. When sintered at 1380 ℃ for 90 min, the maximum relative density of 99.1% is obtained. During liquid sintering, W grains grow up as spherical shape, and the grain size G and sintering time t matches the relationship G3∝ kt, which means that the grain growth of W is subjected to the dissolution-precipitation mechanism. When sintered in the range of 1340~1420 ℃, the grain growth kinetic coefficients increase from 1.61×10?2 to 4.65×10?2μm3/min. The results suggest the formation of liquid, particle rearrangement, dissolution-precipitation and grain growth cause nano-sized W-30Cu composites to reach nearly full density

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郭垚峰,范景蓮,劉 濤. W-30Cu納米復(fù)合粉末液相燒結(jié)致密化與晶粒長大機制[J].稀有金屬材料與工程,2014,43(1):125~129.[Guo Yaofeng, Fan Jinglian, Liu Tao. Densification and Grain Growth Mechanism of Nanosized W-30Cu Powder during Liquid Phase Sintering[J]. Rare Metal Materials and Engineering,2014,43(1):125~129.]
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  • 收稿日期:2013-01-17
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  • 在線發(fā)布日期: 2014-04-16
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