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低W-W連接度65W-25Cu-10Ni合金的制備及準(zhǔn)靜態(tài)力學(xué)性能研究
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北京理工大學(xué)

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TG146.4 11

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國家自然科學(xué)基金項目(面上項目,重點項目,重大項目)


Study on Preparation and Quasistatic Mechanical Properties of 65W-25Cu-10Ni Alloy with Low W-W Contiguity
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Beijing Institute of Technology

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    摘要:

    利用W顆粒表面化學(xué)鍍Ni結(jié)合SPS的方法,制備了低W-W連接度65W-25Cu-10Ni合金,并開展了準(zhǔn)靜態(tài)力學(xué)性能研究。結(jié)果表明,制得的Ni包W復(fù)合粉中Ni包覆層分布均勻且與W結(jié)合良好;以Ni包W復(fù)合粉和Cu粉為原料制備的65W-25Cu-10Ni合金組織均勻且致密。在準(zhǔn)靜態(tài)壓縮加載條件下,與65W-35Cu合金相比,65W-25Cu-10Ni合金的強(qiáng)度及塑性均大幅度提高;在準(zhǔn)靜態(tài)拉伸加載條件下,與65W-35Cu合金相比,65W-25Cu-10Ni合金的強(qiáng)度較高,塑性沒有明顯提高。機(jī)理分析表明,與65W-35Cu合金相比,65W-25Cu-10Ni合金中W-W連接度較低、粘結(jié)相由Cu相轉(zhuǎn)變?yōu)镃u0.81Ni0.19固溶體,且W與粘結(jié)相之間形成了冶金結(jié)合,以上三個因素共同導(dǎo)致65W-25Cu-10Ni合金強(qiáng)度的提高;此外,W-W連接度的降低以及W-粘結(jié)相界面結(jié)合強(qiáng)度的提高是65W-25Cu-10Ni合金在準(zhǔn)靜態(tài)壓縮加載條件下塑性提高的原因。

    Abstract:

    In the present research, W particles were coated using Ni electroless plating technique, and the Ni coated W powders were mixed uniformly with copper powders. 65W-25Cu-10Ni alloy with low W-W contiguity was successfully prepared by SPS method using the composite powders, and the quasistatic mechanical properties were studied. The results show that, after the Ni electroless plating process, Ni is uniformly distributed on the surface of W particles, and the integrating force is strong. The 65W-25Cu-10Ni alloy prepared by SPS method is uniform and dense in microstructure. Compared with 65W-35Cu alloy, 65W-25Cu-10Ni alloy exhibits higher strength and better ductility under quasistatic compression condition, and exhibits higher strength under quasistatic tensile condition, but the ductility under quasistatic tensile condition is not obviously improved. The analysis of the failure mechanism shows that, compared with 65W-35Cu alloy, W-W contiguity is evidently decreased in the 65W-25Cu-10Ni alloy, the matrix is replaced by Cu0.81Ni0.19 solid solution, and metallurgical bonding is formed between W and the matrix, all these above are benefit to increase the strength of 65W-25Cu-10Ni alloy. Meanwhile, the decrease of W-W contiguity and the increase of the interfacial strength are account for ductility increase of 65W-25Cu-10Ni alloy under quasistatic compression condition.

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引用本文

趙紫盈,劉金旭,張鴻雁,郭文啟,李樹奎.低W-W連接度65W-25Cu-10Ni合金的制備及準(zhǔn)靜態(tài)力學(xué)性能研究[J].稀有金屬材料與工程,2016,45(1):182~186.[Zhao Ziying, Liu Jinxu, Zhang Hongyan, Guo Wenqi, Li Shukui. Study on Preparation and Quasistatic Mechanical Properties of 65W-25Cu-10Ni Alloy with Low W-W Contiguity[J]. Rare Metal Materials and Engineering,2016,45(1):182~186.]
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  • 收稿日期:2014-01-14
  • 最后修改日期:2014-02-25
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  • 在線發(fā)布日期: 2019-01-04
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