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冷卻速率及雜質(zhì)元素對鋯合金β→α轉(zhuǎn)變組織的影響
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教育部新世紀(jì)優(yōu)秀人才支持計劃(NCET-08-0606);中央高校基本科研業(yè)務(wù)費(fèi)專項資金(CDJXS10132201);重慶大學(xué)大學(xué)生科研訓(xùn)練計劃(CQU-SRTP-2011354);重慶大學(xué)大型儀器設(shè)備開放基金(2011121507)


Effect of Cooling Rates and Impurities on the Microstructure of β→α Transformation in Zr Alloys
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    摘要:

    鋯合金β相冷卻組織對于發(fā)展高性能燃料包殼具有至關(guān)重要的作用。本工作從冷卻速率和雜質(zhì)元素兩個影響因素出發(fā),對核反應(yīng)堆用鋯合金β → α轉(zhuǎn)變組織的相關(guān)研究進(jìn)行了綜述。鋯合金的馬氏體轉(zhuǎn)變?yōu)闊o擴(kuò)散的切變過程,不產(chǎn)生表面浮凸,Ms不隨冷卻速率變化。成分相同時,隨著β冷卻速率的增加,鋯合金微觀結(jié)構(gòu)按如下次序變化:Lenticular組織→Parallel-plate魏氏組織→Basketweave魏氏組織→馬氏體。相同冷卻速率下,當(dāng)雜質(zhì)元素參與形成難溶的第二相時,會促進(jìn)Basketweave組織的形成,而當(dāng)這些元素提高β轉(zhuǎn)變溫度時,則傾向于促進(jìn)Parallel-plate組織的形成

    Abstract:

    This paper presents a comprehensive review about the effect of cooling rates and impurities on the microstructure of zirconium alloys during β→α transformation with the expectation to facilitate the development of high-performance zirconium-based cladding materials. For zirconium alloys, the diffusionless Martensitic transformation does not produce a surface rumpling after quenching the pre-polished specimens. The Ms temperature keeps independent of β quenching rates. When alloy composition is fixed, increasing of cooling rate causes microstructural change in the following sequence: lenticular α→Parallel plate α→Basketweave α→Martensitic α'. The impurities which can form insoluble second phase particles in β phase will promote the formation of Basketweave Widmanstatten structures. However, the impurities that might increase β phase transformation temperature will lead to more Parallel-plate Widmanstatten structures

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欒佰峰,薛姣姣,柴林江,周 軍.冷卻速率及雜質(zhì)元素對鋯合金β→α轉(zhuǎn)變組織的影響[J].稀有金屬材料與工程,2013,42(12):2636~2640.[Luan Baifeng, Xue Jiaojiao, Chai Linjiang, Zhou Jun. Effect of Cooling Rates and Impurities on the Microstructure of β→α Transformation in Zr Alloys[J]. Rare Metal Materials and Engineering,2013,42(12):2636~2640.]
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  • 收稿日期:2012-12-10
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