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Sc含量對Al-Mg-Sc-Zr合金鑄態(tài)組織及時效強(qiáng)化的影響
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Effects of Sc Content on the Microstructure of the Al-Mg-Sc-Zr as Cast Alloys and Aging Strengthening
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    摘要:

    用金相顯微鏡(OM)、掃描電鏡(SEM)、透射電鏡(TEM)及顯微硬度儀研究了Sc含量對Al-5.5Mg-0.5Mn-XSc-0.1Zr (質(zhì)量分?jǐn)?shù),%) (0.05≤X≤0.50)合金鑄態(tài)顯微組織和時效處理后二次析出相的形貌及其強(qiáng)化作用的影響。結(jié)果表明:當(dāng)Sc含量少于0.09%(質(zhì)量分?jǐn)?shù),下同)時,凝固過程中無含Sc相析出,鑄錠組織為柱狀樹枝晶,時效后強(qiáng)化作用有限;當(dāng)Sc含量在0.16%~0.23%時,凝固過程中析出少量初生及共晶Al3(Sc, Zr)相,這既能夠細(xì)化晶粒,又不影響時效后二次析出相的熱穩(wěn)定性,時效后合金的硬度也較高;而Sc含量過高(X≥0.23)時,合金中初生和共晶Al3(Sc, Zr)相的含量增多,雖然也能夠細(xì)化晶粒,但凝固后基體中固溶的Zr含量也會隨之降低,導(dǎo)致二次Al3(Sc, Zr)相的熱穩(wěn)定性降低,450 ℃時效24 h后二次析出相粗化嚴(yán)重,強(qiáng)化作用很弱

    Abstract:

    The influences of Sc contents on the microstructures of Al-5.5Mg-0.5Mn-XSc-0.1Zr (0.05≤X≤0.50) as cast alloy and the morphologies of the second Al3(Sc,Zr) precipitates as well as their strengthening effect after aging treatment were investigated by optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and micro-hardness tester. The results show that when X≤0.09, no precipitates containing Sc are found in as cast alloy. On this case, the alloy possesses the typical columnar dendritic microstructure, and the strengthening effect after the aging treatment is weak. While for the alloy with 0.16%~0.23% Sc, primary and eutectic Al3(Sc,Zr) particles precipitate during solidification, which not only refine grains, but also not impair the thermal stability of the second Al3(Sc,Zr) precipitates, and the strengthening effect is strong. When X≥0.23, a large volume of primary and eutectic Al3(Sc,Zr) particles precipitate. Though this can refine the grains strongly, but a side effect is that the Zr content in the alloys after solidification would be severely decreased, resulting in the second Al3(Sc,Zr) precipitates becoming less thermal stable. After aging at 450 ℃ for 24 h, the second Al3(Sc,Zr) precipitates coarse a lot, and its strengthening effect becomes very weak

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楊 文,閆德勝,戎利建. Sc含量對Al-Mg-Sc-Zr合金鑄態(tài)組織及時效強(qiáng)化的影響[J].稀有金屬材料與工程,2013,42(12):2530~2535.[Yang Wen, Yan Desheng, Rong Lijian. Effects of Sc Content on the Microstructure of the Al-Mg-Sc-Zr as Cast Alloys and Aging Strengthening[J]. Rare Metal Materials and Engineering,2013,42(12):2530~2535.]
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  • 收稿日期:2012-12-21
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