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Ag45CuZn釬料表面刷鍍錫的試驗(yàn)研究
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國(guó)家重點(diǎn)基礎(chǔ)研究發(fā)展計(jì)劃(“973”計(jì)劃)項(xiàng)目(2012CB723902);國(guó)家高技術(shù)研究發(fā)展計(jì)劃(“863”計(jì)劃)項(xiàng)目(2012AA040208)


Experimental Research of Tin Brush Electro-Plated on Ag45CuZn Brazing Filler Metal
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    摘要:

    以Ag45CuZn 釬料為基體,在其表面刷鍍錫制備AgCuZnSn釬料,考察電流密度、陰陽(yáng)極相對(duì)運(yùn)動(dòng)速度、鍍液溫度、刷鍍電壓和時(shí)間對(duì)刷鍍電流效率和AgCuZnSn釬料中Sn含量的影響,采用掃描電鏡(SEM)和潤(rùn)濕試驗(yàn)爐分析錫鍍層的表面形貌和釬料的潤(rùn)濕性。結(jié)果表明,隨著電流密度、刷鍍電壓及鍍液溫度的升高,電流效率和Sn含量先增大后減小;隨著陰陽(yáng)極相對(duì)運(yùn)動(dòng)速度的增加,電流效率逐漸降低,Sn含量先升高后下降;隨著刷鍍時(shí)間的延長(zhǎng),Sn含量逐漸增加,電流效率無(wú)顯著變化。無(wú)定向錫顆粒平行于Ag45CuZn 釬料表面方向的生長(zhǎng)方式優(yōu)于垂直其表面方向的生長(zhǎng)方式,此時(shí)鍍層表面平整、致密,孔隙率小(0.82 %),錫晶粒的尺寸為0.3~1.8 μm。與基體Ag45CuZn釬料相比,刷鍍2.38%(質(zhì)量分?jǐn)?shù))金屬Sn之后,其潤(rùn)濕面積提高19.5 %,制備的Ag43.92Cu28.65Zn25.05Sn2.38釬料具有良好的潤(rùn)濕性

    Abstract:

    The AgCuZnSn brazing filler metal was prepared on the Ag45CuZn brazing filler metal by brush electro-plating tin. The effect of current density, relative velocity of cathode and anode, bath electrolyte temperature, voltage and time on current efficiency and tin content of AgCuZnSn brazing filler metal were investigated. The surface morphology of tin coating and the brazing filler metal wettability were observed using scanning electron microscopy (SEM) and wetting test furnace. The results indicate that current efficiency and tin content initially increase and then decrease with the increase of the current density, brush electro-plating voltage and temperature. As the increase of the relative velocity of anode and cathode, the current efficiency gradually reduces, and the tin content initially increases and then decreases. With the increase of the brush electro-plating time, the current efficiency has no significant change, but the content of tin increases. SEM images show that a smooth and uniform surface morphology of the tin coating with tin grain size of about 0.3~1.8 μm and porosity of 0.82% is obtained. The non-directional tin granular parallel to the surface direction of Ag45CuZn brazing filler metal growth is better than that of perpendicular to the surface of the growth. Compared to Ag45CuZn brazing filler metal matrix, when 2.38 wt.% metal tin is brush electro-plated on Ag45CuZn brazing filler metal, the wetting area of Ag45CuZn brazing filler metal increases by about 19.5 %, and the Ag43.92Cu28.65Zn25.05Sn2.38 brazing filler metal possesses a good wettability

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王星星,張冠星,龍偉民,沈元?jiǎng)?裴夤崟,呂登峰. Ag45CuZn釬料表面刷鍍錫的試驗(yàn)研究[J].稀有金屬材料與工程,2013,42(11):2394~2399.[Wang Xingxing, Zhang Guanxing, Long Weimin, Shen Yuanxun, Pei Yinyin, Lü Dengfeng. Experimental Research of Tin Brush Electro-Plated on Ag45CuZn Brazing Filler Metal[J]. Rare Metal Materials and Engineering,2013,42(11):2394~2399.]
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  • 收稿日期:2012-11-25
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