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TiO2納米管/Ti光陽(yáng)極的氫化處理及其光解水性能
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國(guó)家自然科學(xué)基金 (50902115)


Hydrogen Treated TiO2 Nanotube/Ti Photoanode and Its Photospliting Water Property
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    摘要:

    氫化處理TiO2納米管是一種簡(jiǎn)單而又有效地提高其光解水制氫效率的方法。通過(guò)采用FE-SEM、TEM、XRD及XPS等研究,在大氣氣氛500 ℃熱處理后,接著經(jīng)300 ℃氫化處理后,獲得了由以銳鈦礦組成的TiO2 納米管壁,和在納米管內(nèi)壁上高度無(wú)序的表面層組成的雙相結(jié)構(gòu)的TiO2 納米管陣列,且在納米管表面形成了Ti-OH能帶。光催化分解水試驗(yàn)表明,在光強(qiáng)為100 mW/cm2的模擬太陽(yáng)光照射下氫化處理后的TiO2納米管光陽(yáng)極的光電流密度可達(dá)4.88 mA/cm2,較未氫化處理的樣品提高了約4倍

    Abstract:

    TiO2 nanotubes were prepared by annealing the as-prepared samples in air at 500 ℃, and then in hydrogen atmosphere at 300 ?C. Hydrogenated TiO2 nanotube arrays were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction microscopy (XRD), and X-ray photoelectron spectroscopy (XPS). Results show that hydrogen-treated TiO2 nanotube arrays areconsisted of anatase phase TiO2 nanotube walls and disordered nanophase in the surface of TiO2 nanotube walls. It is demonstrated that the presence of the Ti-OH energy states in disordered nanophase. The hydrogenated TiO2 nanotube sample yields a photocurrent density of ~4.88 mA/cm2 vs Ag/AgCl, in 1 mol/L NaOH solution under the illumination of simulated solar light (100 mW/cm2 from lamp coupled with an AM 1.5 G filter). Remarkably, a 4-fold enhanced photocurrent density for TiO2 nanotubes after hydrogen treatment was observed

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李廣忠,湯慧萍,張文彥,李 綱,趙 培. TiO2納米管/Ti光陽(yáng)極的氫化處理及其光解水性能[J].稀有金屬材料與工程,2013,42(11):2341~2345.[Li Guangzhong, Tang Huiping, Zhang Wenyan, Li Gang, Zhao Pei. Hydrogen Treated TiO2 Nanotube/Ti Photoanode and Its Photospliting Water Property[J]. Rare Metal Materials and Engineering,2013,42(11):2341~2345.]
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  • 收稿日期:2012-11-20
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