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添加Al對Cu-Ni-Cr合金高溫氧化行為的影響
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國家自然科學(xué)基金(50771068,51271127);遼寧省高等學(xué)校優(yōu)秀人才支持計(jì)劃(LR2011032)


Effect of Al Addition on High Temperature Oxidation Behavior of Cu-Ni-Cr Alloy
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    摘要:

    研究了Cu-40Ni-12Cr-2.5Al合金在700~800 ℃純氧氣中的氧化行為以及添加Al對Cu-Ni-Cr合金氧化行為的影響。結(jié)果表明:合金氧化動力學(xué)偏離拋物線規(guī)律,800 ℃時(shí)的氧化增重明顯低于700 ℃,兩種溫度下的氧化增重與前面研究的Cu-40Ni-20Cr合金相比明顯降低;合金表面形成的氧化膜外層主要是不連續(xù)Cu的氧化物層,緊接著是Cu、Ni、Cr和Al的混合氧化物層,而在合金內(nèi)部形成了連續(xù)且具有保護(hù)性的Cr2O3膜??梢姡砑拥?組元Al到Cu-Ni-Cr合金后,活潑組元Cr由合金內(nèi)部向外擴(kuò)散的速度加快,因此在較低Cr含量下合金能形成連續(xù)的Cr2O3膜

    Abstract:

    The oxidation of a quaternary two-phase Cu-40Ni-12Cr-2.5Al alloy formed by the 2.5at% Al addition to Cu-Ni-Cr alloy were investigated at 700~800 oC in 0.1 MPa pure oxygen, and the effect of adding the forth component Al on the oxidation of Cu-Ni-Cr alloy was also discussed. Results show that kinetic curves of the present alloy deviate considerably from the parabolic rate law and the mass gain at 700 oC is higher than that at 800 oC. Moreover, the mass gain of the Cu-40Ni-12Cr-2.5Al alloy is lower than that of the Cu-40Ni-20Cr alloy evidently. The Cu-40Ni-12Cr-2.5Al alloy form uncontinuous external CuO scales followed by the mixed scales composed of Cu, Ni and Cr oxides. Finally, the alloys form a very thin and continuous Cr2O3 scales in contact with the alloy. Obviously, adding the forth component Al to Cu-Ni-Cr alloy is able to decrease the critical content to form Cr oxide and facilitates the formation of continuous Cr2O3 scales under much lower Cr content in spite of the simultaneous presence of two phase in the alloy.

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曹中秋,于 龍,張 軻.添加Al對Cu-Ni-Cr合金高溫氧化行為的影響[J].稀有金屬材料與工程,2013,42(10):2149~2152.[Cao Zhongqiu, Yu Long, Zhang Ke. Effect of Al Addition on High Temperature Oxidation Behavior of Cu-Ni-Cr Alloy[J]. Rare Metal Materials and Engineering,2013,42(10):2149~2152.]
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  • 收稿日期:2012-11-16
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