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納米鎂基儲氫材料對AP熱分解性能的影響
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上海市科委基礎(chǔ)研究重點項目(10JC1407700);上海市自然科學(xué)基金(11ZR1417600)及重大專項(10DZ2211000);教育部博士點新教師基金項目(20100073120007)


Effect of Nano-magnesium Based Hydrogen Storage Materials on Thermal Decomposition of Ammonium Perchlorate
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    采用直流電弧等離子體加高壓氫化法制備了納米鎂基儲氫材料Mg-H和MgEr-H,并對其相組成和放氫性能進行了表征,結(jié)果表明添加稀土元素Er可使Mg粉的吸氫更完全,同時使MgH2的放氫溫度降低。采用同步熱分析方法(TG/DSC)分析了鎂基儲氫材料對高氯酸銨(AP)熱分解性能的影響,結(jié)果表明兩種鎂基儲氫材料都能有效促進AP的低溫和高溫分解過程,尤其是高溫分解峰溫下降了約80 ℃,并且使得表觀放熱量大幅增加,可達純AP放熱量的2倍多,反應(yīng)過程更為劇烈。添加稀土的鎂基儲氫材料對AP分解的催化效果更好

    Abstract:

    Magnesium based hydrogen storage nanomaterials, Mg-H and MgEr-H, were prepared through the DC arc plasma method followed by hydrogenation under high hydrogen pressure. The phase composition and dehydriding properties of the hydrogenated nanopowders were analyzed. It is revealed that Er addition can effectively increase the hydrogen absorption percentage of Mg powder and reduce the dehydriding temperature. The thermal decomposition behaviors of pure ammonium perchlorate (AP) and AP with the presence of the magnesium based hydrogen storage nanomaterials have been investigated by simultaneous thermal analysis (TG-DSC). The results show that both Mg-H and MgEr-H can promote the thermal decomposition of AP, including the low temperature reaction and the high temperature reaction. Particularly for the high temperature decomposition, the temperature can be decreased by 80 oC. The decomposition heat of AP is increased greatly, around twice of that of the pure AP, and the reaction rate is also much faster. Therefore, the magnesium based hydrogen storage nanomaterials with rare earth addition are good catalysts for the decomposition of AP

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李龍津,鄒建新,曾小勤,堵 平,丁文江.納米鎂基儲氫材料對AP熱分解性能的影響[J].稀有金屬材料與工程,2013,42(7):1445~1449.[Li Longjin, Zou Jianxin, Zeng Xiaoqin, Du Ping, Ding Wenjiang. Effect of Nano-magnesium Based Hydrogen Storage Materials on Thermal Decomposition of Ammonium Perchlorate[J]. Rare Metal Materials and Engineering,2013,42(7):1445~1449.]
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  • 收稿日期:2012-07-14
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