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Y對Mg-8Li-4Zn-xY合金及其1 mm薄板組織與性能的影響
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西北工業(yè)大學(xué)凝固技術(shù)國家重點實驗室開放課題(SKLSP201002);陜西省教育廳科研計劃項目 (2010JK764, 2010JK769); 陜西省科技計劃(工業(yè)攻關(guān))項目(2010K10-08);陜西省重點學(xué)科建設(shè)專項資金資助項目;西安理工大學(xué)科學(xué)研究計劃項目(101-210911)


Effects of Y on Microstructure and Mechanical Properties of Mg-8Li-4Zn-xY Magnesium Alloy and Its 1 mm Thick Sheet
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    摘要:

    采用鋰鹽熔劑保護熔鑄了Mg-8Li-4Zn-xY合金鑄錠,并通過正擠壓制成1 mm的薄板。通過光學(xué)顯微鏡、掃描電鏡、XRD分析及合金硬度測試,探討合金的組織與力學(xué)性能。結(jié)果表明:Mg-8Li-4Zn-xY合金基體為β-Li (bcc)和α-Mg (hcp)相,析出強化相顆粒和化合物為Mg2Zn11,Mg72.05Zn27.95,MgZn,Mg2Y,MgY及未知相。隨Y含量的增加,鑄態(tài)基體組織得到細化,析出相數(shù)量增加。1 mm正擠壓變形態(tài)薄板材基體組織大小、形貌和β-Li相內(nèi)彌散析出的強化相顆粒數(shù)量隨著Y含量的提高沒有明顯變化,但α-Mg相由β-Li相包裹著被拉長并得到一定程度的細化,呈平行于擠壓方向的條帶狀。β-Li相在協(xié)調(diào)塑性變形的同時發(fā)生了動態(tài)再結(jié)晶,晶界均勻分布著強化相顆粒。無論是鑄態(tài)還是擠壓后1 mm的Mg-8Li-4Zn-xY合金薄板,隨著Y含量的增加合金得到不同程度的強化,硬度均得到不同程度的提高。

    Abstract:

    As-cast ingots of Mg-8Li-4Zn-xY magnesium alloy were prepared by lithium flux protection in an electric-resistance furnace, and 1 mm thick sheets were prepared by forward extrusion. Microstructures and mechanical properties of the alloy were investigated with OM, SEM equipped with an energy-dispersive X-ray spectroscopy (EDS), XRD and the HV-120 hardness Vickers. The results show that the matrix of as-cast Mg-8Li-4Zn-xY alloy consists of α-Mg (hexagonal close-packed) and β-Li (body-centered cubic) phase. The precipitation strengthening phase particles and compounds are Mg2Zn11, Mg72.05Zn27.95, MgZn, Mg2Y, MgY and unknown phase. The matrixes of Mg-8Li-4Zn-xY magnesium alloy ingots are refined and the amount of the precipitation strengthening phase are enhanced along with the yttrium content increasing, but there is no appreciable changing of the matrix size, appearance and dispersion precipitation phases in β-Li phase. On the contrary, the α-Mg phases wrapped by β-Li phase are elongated and refined during the extrusion process, and paralleled to the extrusion direction as stripped. The β-Li phases could coordinate plastic deformation and synchronize dynamic recrystallization, and the strengthening phases are of uniform distribution on the crystal boundary. The ingots and 1 mm thick sheets of Mg-8Li-4Zn-xY alloys are strengthened and the hardnesses are also enhanced in different extent along with the yttrium content increasing.

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徐春杰,馬 濤,王錦程,屠 濤,張忠明. Y對Mg-8Li-4Zn-xY合金及其1 mm薄板組織與性能的影響[J].稀有金屬材料與工程,2013,42(6):1226~1230.[Xu Chunjie, Ma Tao, Wang Jincheng, Tu Tao, Zhang Zhongming. Effects of Y on Microstructure and Mechanical Properties of Mg-8Li-4Zn-xY Magnesium Alloy and Its 1 mm Thick Sheet[J]. Rare Metal Materials and Engineering,2013,42(6):1226~1230.]
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  • 收稿日期:2012-06-15
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