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Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu合金在400 ℃過(guò)熱蒸氣中的耐腐蝕性能
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國(guó)家自然科學(xué)基金項(xiàng)目(50871064,50971084);上海市重點(diǎn)學(xué)科建設(shè)項(xiàng)目(S30107)


Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu合金在400 ℃過(guò)熱蒸氣中的耐腐蝕性能
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    摘要:

    采用靜態(tài)高壓釜腐蝕試驗(yàn)研究了Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu(x=0.05~0.5,質(zhì)量分?jǐn)?shù),%)合金在400 ℃,10.3 MPa過(guò)熱蒸氣中的耐腐蝕性能,用TEM和SEM分別觀察了合金的顯微組織和氧化膜的斷口形貌。結(jié)果表明:當(dāng)Cu含量不超過(guò)0.2%時(shí),合金中析出的第二相主要是尺寸較小的Zr(Fe,Cr,Nb)2型和少量尺寸相對(duì)較大的含Cu的Zr3Fe型;當(dāng)Cu含量超過(guò)0.2%時(shí),合金中析出了Zr2Cu型第二相,隨著Cu含量的增加,Zr2Cu型第二相尺寸增大,數(shù)量增多;在添加0.05%Cu的合金中就有含Cu第二相的析出,說(shuō)明Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu合金a-Zr基體中固溶的Cu含量很低。當(dāng)Cu含量不超過(guò)0.35%時(shí),合金的的耐腐蝕性能基本沒(méi)有差別;但是當(dāng)Cu含量達(dá)到0.5%時(shí),由于合金中析出了尺寸較大、數(shù)量較多的Zr2Cu型第二相,致使合金的耐腐蝕性能變差。

    Abstract:

    The effect of Cu content on the corrosion resistance of Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu alloys (x=0.05~0.5, mass fraction, %) was investigated in superheated steam at 400 oC and 10.3 MPa by autoclave tests. The microstructure of the alloys and the fracture surface of oxide films on the corroded specimens were observed by TEM and SEM, respectively. The results show that when the addition of Cu is below 0.2%, the second phase particles (SPPs) are mainly Zr(Fe,Cr,Nb)2 in smaller size, and few Zr3Fe with Cu. When the addition of Cu is above 0.2%, the SPPs of Zr2Cu are precipitated. The Zr2Cu particles become larger in size and more in amount with the increase of Cu content. The precipitates containing Cu are found in the alloy even with 0.05% Cu, which indicates that the Cu concentration in α-Zr matrix is very small. Cu addition of 0.05%~0.35% has little effect on the corrosion resistance of the alloys, but when the addition of Cu reaches 0.5%, the corrosion resistance of the alloy decreases, which is the worst one among the alloys.

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張 欣,姚美意,李中奎,周 軍,李 強(qiáng),周邦新. Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu合金在400 ℃過(guò)熱蒸氣中的耐腐蝕性能[J].稀有金屬材料與工程,2013,42(6):1210~1214.[Zhang Xin, Yao Meiyi, Li Zhongkui, Zhou Jun, Li Qiang, Zhou Bangxin. Zr-0.80Sn-0.4Nb-0.4Fe-0.10Cr-xCu合金在400 ℃過(guò)熱蒸氣中的耐腐蝕性能[J]. Rare Metal Materials and Engineering,2013,42(6):1210~1214.]
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  • 收稿日期:2012-06-15
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