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快速-熱擠壓工藝對細晶和傳統(tǒng)鎢合金組織與性能的影響
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國家杰出青年科學基金(50925416);國家自然科學基金創(chuàng)新群體項目資助(51074187)


Effect of Rapid Hot Extrusion on Microstructure and Mechanical Properties of Fine-Grained Tungsten Alloy and Coarse-Grained Tungsten Alloy
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    摘要:

    研究了快速-熱擠壓工藝對細晶93W-4.9Ni-2.1Fe、細晶93W-4.9Ni-2.1Fe+0.03%Y以及傳統(tǒng)粗晶93W-4.9Ni-2.1Fe合金的顯微組織和力學性能的影響。結(jié)果表明:經(jīng)過快速熱擠壓后,合金的綜合力學性能較燒結(jié)態(tài)合金顯著提高,而且初始晶粒尺寸對擠壓后合金性能影響非常顯著,在相同的擠壓條件下,擠壓態(tài)細晶93W-4.9Ni-2.1Fe+0.03%Y的抗拉強度達到1570 MPa,延伸率為6.5%,硬度HRC45.2;而擠壓態(tài)傳統(tǒng)93W-4.9Ni-2.1Fe合金的抗拉強度、延伸率和硬度分別只有1260 MPa、5.6%和39.1。顯微組織觀察分析表明,與傳統(tǒng)鎢合金相比,在相同變形量的情況下,細晶93W-4.9Ni-2.1Fe+0.03%Y鎢合金的纖維化程度更高,鎢顆粒長細比達到6.8。TEM觀察表明擠壓后細晶鎢合金的鎢相形成了亞晶組織,而傳統(tǒng)鎢合金有大量位錯纏結(jié)于鎢相中;此外,由于充分的動態(tài)回復-再結(jié)晶,細晶和傳統(tǒng)鎢合金的粘結(jié)相位錯密度很低。

    Abstract:

    The effect of rapid hot extrusion on the microstructure and mechanical properties of fine-grained (10~20 μm) 93W-4.9Ni-2.1Fe, fine-grained 93W-4.9Ni-2.1Fe+0.03%Y and traditional coarse-grained (40~45 μm) 93W-4.9Ni-2.1Fe alloy was investigated. The results show that after rapid hot extrusion, the comprehensive mechanical properties of the alloys are significantly enhanced compared with the as-sintered alloys. The initial grain size has a profound effect on the mechanical properties of as-extruded alloys. With the same extrusion processing parameters, the ultimate tensile strength (UTS), elongation and hardness of the as-extruded fine-grained 93W-4.9Ni-2.1Fe+0.03%Y alloy reached 1570 MPa, 6.5% and 45.2 (HRC) respectively. However, the ultimate tensile strength (UTS), elongation and hardness of the as-extruded coarse-grained alloy were 1260 MPa, 5.6% and 39.1. Microstructure observation shows that compared with the traditional coarse-grained alloy, the fibrous degree of the as-extruded fine-grained alloy is much larger under the condition of the same deformation degree. Moreover, the aspect ratio of the tungsten particles in the as-extruded fine-grained 93W-4.9Ni-2.1Fe+0.03%Y alloy achieves 6.8, which is one time larger than that of the as-extruded traditional coarse-grained alloy. TEM shows that after hot extrusion, many subgrains could be observed in fine-grained tungsten phase and numerical dislocations tangled in coarse-grained tungsten phase. In addition, the dislocation density of both kind of matrix is low because of sufficient dynamical recovery-recrystallization.

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范景蓮,楊昌麟,龔 星,丁 飛.快速-熱擠壓工藝對細晶和傳統(tǒng)鎢合金組織與性能的影響[J].稀有金屬材料與工程,2013,42(2):372~376.[Fan Jinglian, Yang Changlin, Gong Xing, Ding Fei. Effect of Rapid Hot Extrusion on Microstructure and Mechanical Properties of Fine-Grained Tungsten Alloy and Coarse-Grained Tungsten Alloy[J]. Rare Metal Materials and Engineering,2013,42(2):372~376.]
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  • 收稿日期:2012-02-09
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