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鎂鋰合金表面高錳酸鹽轉化膜的研究
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哈爾濱市科技創(chuàng)新人才研究專項資金(2010RFQXG037)


Permanganate Conversion Coatings on Magnesium Lithium Alloy Surface
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    摘要:

    采用化學轉化法在鎂鋰合金表面制得了結構致密、耐蝕性能較好的高錳酸鹽轉化膜,研究了轉化液中高錳酸鹽溶液濃度對成膜效果的影響。實驗采用掃描電子顯微鏡(SEM)、X射線衍射儀(XRD)和X射線光電子能譜(XPS)對所制得轉化膜的表面形貌、結構和組成進行了測試。同時,使用動電位極化曲線、電化學交流阻抗譜和腐蝕失重3種方法對鎂鋰合金及其轉化膜的耐腐蝕性能進行了深入研究。結果表明:高錳酸鹽轉化膜較均勻、平整,間隙較小,轉化膜主要由錳的氧化物組成。提高了鎂鋰合金的耐腐蝕性能,當高錳酸鹽溶液濃度為4.0 g/L時,轉化膜的腐蝕電流密度小、容抗弧大、腐蝕速率低,耐腐蝕性能佳。

    Abstract:

    Compact conversion coatings with much better corrosion resistance for Mg-8.5Li alloy were obtained by immersing in a solution of permanganate. The concentration of potassium permanganate was discussed. The surface morphology of the conversion coatings was observed by scanning electron microscopy (SEM), and the chemical composition was characterized by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The corrosion resistance of Mg-8.5Li alloy and permanganate conversion coatings were investigated by means of potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and mass loss measurement. The results show that the coatings with cracked morphology are homogeneous and uniform. The corrosion resistance of permanganate conversion coatings is improved greatly compared with that of Mg-8.5Li alloy. When the concentration of permanganate is 4.0 g/L, the corrosion current density is the smallest, capacitance arc is the biggest and corrosion rate reaches minimum and the conversion coating presents the best corrosion resistance behavior.

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李玲莉,趙 剛,朱麗葉,應麗霞,王桂香.鎂鋰合金表面高錳酸鹽轉化膜的研究[J].稀有金屬材料與工程,2013,42(2):345~348.[Li Lingli, Zhao Gang, Zhu Liye, Ying Lixia, Wang Guixiang. Permanganate Conversion Coatings on Magnesium Lithium Alloy Surface[J]. Rare Metal Materials and Engineering,2013,42(2):345~348.]
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  • 收稿日期:2012-05-28
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