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硼置換鋁對CaAl2Si2O8:Eu2+結(jié)構(gòu)和發(fā)光特性的影響
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國家自然科學(xué)基金資助(20771086)


Effect of Substituting B for Al on Structure and Spectral Properties of Phosphors CaAl2Si2O8: Eu2+
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    摘要:

    采用高溫固相法在弱還原氣氛下制備Ca0.955Al2-xBxSi2O8:Eu2+(x= 0~0.7)系列熒光粉,研究BⅢ置換AlⅢ對晶體結(jié)構(gòu)和光譜特性的影響。BⅢ以類質(zhì)同相替代CaAl2Si2O8晶格中的AlⅢ形成連續(xù)固溶體,晶胞參數(shù)a,b,c,γ和晶胞體積V呈線性遞減,而晶面夾角α,β呈線性遞增。熒光激發(fā)譜為225~420 nm寬帶激發(fā)譜,半高寬為112 nm,表觀峰位于352 nm,隨著BⅢ置換量的增加,半高寬從112 nm減小到95 nm。發(fā)射光譜位于370~600 nm,可由423和460 nm兩峰擬合而成,表觀峰值位于425 nm,隨著BⅢ置換量的增加,兩擬合峰均線性藍(lán)移,且擬合峰強(qiáng)度比呈線性遞減

    Abstract:

    A series of luminescence phosphors Ca0.955Al2-xBxSi2O8: Eu2+ (x=0~0.7) were prepared by solid-state reaction in weak reductive atmosphere. The lattice positions and the luminescent mechanism of Eu2+ in the host were discussed. The effects of BⅢ-substitution on the host lattices and spectral properties were also investigated. It is found that when BⅢ enters CaAl2Si2O8 lattice and substitutes AlⅢ, complete solid solutions are formed in the whole range of x = 0~0.7. The lattice parameters (a, b, c, γ) and unit cell volumes of phosphors Ca0.955Al2-xGaxSi2O8:Eu2+ (x=0~1.0) decrease linearly and the lattice parameters(α,β) increase linearly as BⅢ content increases. A broad excitation spectrum consists of four excitation bands, which are located between 225 nm and 420 nm,the maximum excitation wavelength of which is at 352 nm,and FWHM decreases from 112 nm to 95 nm with the increase of the substitution amount of BⅢ. The emission spectrum, which is also a broad band between 370 nm and 600 nm,can be fitted by two peaks at 423 nm and 460 nm and its apparent peak is at 425 nm. Two fitted peaks are blue shifted, and the intensity ratio of the fitted peaks decreases linearly with increasing of the amount of BⅢ-substitution

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王 飛,田一光,張 喬,趙文光.硼置換鋁對CaAl2Si2O8:Eu2+結(jié)構(gòu)和發(fā)光特性的影響[J].稀有金屬材料與工程,2012,41(8):1472~1476.[Wang Fei, Tian Yiguang, Zhang Qiao, Zhao Wenguang. Effect of Substituting B for Al on Structure and Spectral Properties of Phosphors CaAl2Si2O8: Eu2+[J]. Rare Metal Materials and Engineering,2012,41(8):1472~1476.]
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  • 收稿日期:2011-09-05
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