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相場(chǎng)法研究彈性畸變能對(duì)Ni-Al合金有序化過程的影響
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國(guó)家自然科學(xué)基金(10902086, 50875217, 50941020);西北工業(yè)大學(xué)基礎(chǔ)研究基金 (NPU-FFR-JC201005)


Study on the Effect of Elastic Strain Energy on the Ordering Process of Ni-Al Alloy by Phase-Field
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    摘要:

    采用微觀彈性相場(chǎng)動(dòng)力學(xué)模型,研究由共格錯(cuò)配產(chǎn)生的彈性畸變能對(duì)Ni-Al合金沉淀過程中γ′(Ni3Al) 相有序化過程的影響。模擬結(jié)果表明,對(duì)于不同的沉淀機(jī)制,如非經(jīng)典形核、非經(jīng)典形核與失穩(wěn)分解的混合機(jī)制及失穩(wěn)有序化,彈性畸變能均阻礙Al原子在β格點(diǎn)的占位,從而阻礙有序化過程的進(jìn)行。同一時(shí)間步長(zhǎng)下,考慮彈性畸變能的合金,其γ′相內(nèi)濃度和長(zhǎng)程序參數(shù)曲線的高度和寬度均小于忽略彈性畸變能的合金,曲線分布更加彌散。彈性畸變能改變了γ′相的空間排列及微觀形貌,最終形成沿彈性“軟方向”擇優(yōu)排列的共格微觀組織。

    Abstract:

    Using the phase-field microelasticity model, we studied the effect of elastic strain energy (ESE) resulted from the precipitation misfit on the ordering process of γ′ (Ni3Al) phase. The simulation results show that ESE always presents impediment effect for different precipitation mechanisms, such as non-classical nucleation, the mixed style of non-classical nucleation and spinodal decomposition, spinodal ordering; and slows down the occupation probability (OP) of Al atom at β site, and impedes the ordering process. At the same time step, the height and the width of the concentration and long-range order parameter (LROP) are small in the system involving ESE.ESE changes the spatial arrangement and microstructure, and leads to the preferred orientation microstructure.

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盧艷麗,陳 錚,王永欣,張 靜,楊 坤.相場(chǎng)法研究彈性畸變能對(duì)Ni-Al合金有序化過程的影響[J].稀有金屬材料與工程,2012,41(7):1216~1220.[Lu Yanli, Chen Zheng, Wang Yongxin, Zhang Jing, Yang Kun. Study on the Effect of Elastic Strain Energy on the Ordering Process of Ni-Al Alloy by Phase-Field[J]. Rare Metal Materials and Engineering,2012,41(7):1216~1220.]
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  • 收稿日期:2011-07-12
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