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FGH95合金長期時效過程中二次γ′相的“反粗化”分裂行為
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國家重點(diǎn)基礎(chǔ)研究發(fā)展計劃(2010CB631200, 2010CB631204)


Reverse Coarsening Splitting Behavior of the Secondary γ′ in Superalloy FGH 95 during Long-Term Aging
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    摘要:

    利用場發(fā)射掃描電鏡研究了FGH95粉末冶金高溫合金在750 ℃/5000 h時效過程中二次γ′相的尺寸、分布和形貌變化,為其在新型航空發(fā)動機(jī)中的應(yīng)用提供理論依據(jù)。結(jié)果表明,隨著時效時間增加,二次γ′相形態(tài)不穩(wěn)定,其尺寸變化不符合體擴(kuò)散控制的LSW規(guī)律。二次γ′相在0~500 h發(fā)生“反粗化”的分裂,由碟狀分裂為塊狀。在500~1000 h階段分裂的細(xì)小γ′相發(fā)生粗化,在1000 h粗化到一定程度后又開始分裂,2000 h后隨著時效時間延長又逐漸粗化,橢球狀二次γ′相逐漸增多。研究證明,γ′相粒子之間的彈性交互作用是導(dǎo)致其形態(tài)變化的主要原因,它屬于降低界面能與彈性交互作用能總量的形貌轉(zhuǎn)變機(jī)制。

    Abstract:

    The size, the distribution and the shape of secondary γ′ in powder metallurgy superalloy FGH95 were researched by field emission scanning electron microscopy, the alloy was long-term aged at 750 °C for 5000 h, in order to provide a theoretical basis for its application in newly aero-engines. The results show that with prolonging of the aging time, the morphological character of secondary γ' is unstable, and its size does not follow the law of LSW theory. During 0~500 h the splitting of reverse coarsening occurs in the second γ', resulting in splitting of a single butterfly precipitate into a group of eight cuboids. In 500~1000 h, the split γ′ coarsens to a certain extent and then start to split again after 1000 h. With prolonging of the aging time, they gradually grow after 2000 h, ellipsoidal secondary γ' phase become more and more. It is proved that the shape evolution strongly depends on the elastic interaction between γ' precipitates. Shape changes in order to minimize the sum of interfacial and elastic interaction energies.

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賈 建,陶 宇,張義文,張 瑩. FGH95合金長期時效過程中二次γ′相的“反粗化”分裂行為[J].稀有金屬材料與工程,2012,41(7):1156~1160.[Jia Jian, Tao Yu, Zhang Yiwen, Zhang Ying. Reverse Coarsening Splitting Behavior of the Secondary γ′ in Superalloy FGH 95 during Long-Term Aging[J]. Rare Metal Materials and Engineering,2012,41(7):1156~1160.]
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  • 收稿日期:2011-07-11
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