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Nickel Release of 10 K White Gold Alloy for Jewelry
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Nickel Release of 10 K White Gold Alloy for Jewelry
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Guangzhou Education Bureau Project (08C013); First Construction Innovation Academic Team of Guangzhou Education System (Sui Jiao Ke 2009)

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    摘要:

    白色金合金飾品廣泛使用鎳作為漂白元素,可以獲得較好的顏色和機(jī)械性能。但是鎳是一個(gè)潛在的致敏元素。本文選擇一種常用的所謂“無鎳過敏”10 K白金合金首飾材料,按照EN1811標(biāo)準(zhǔn)檢測(cè)了不同加工條件和表面處理方式下的鎳釋放情況。結(jié)果表明,合金的鎳釋放率與其耐腐蝕性密切相關(guān),同種合金材料采用不同的加工工藝和表面處理方式,鎳釋放率不同,呈現(xiàn)“兩相區(qū)退火態(tài)+粗糙面>冷加工態(tài)+粗糙面>冷加工態(tài)+拋光面>淬火態(tài)+粗糙面>淬火低溫回火態(tài)+粗糙面”的順序; 盡管試驗(yàn)合金的鎳釋放率調(diào)整值滿足鎳指令“94/27/EC”的要求, 但絕大部分不能通過鎳指令“2004/96/EC”,尤其是在各種工藝條件下的實(shí)際鎳釋放率均明顯超過兩個(gè)鎳指令中規(guī)定的閾值,說明用這種材料制作的飾品在使用過程中存在鎳過敏風(fēng)險(xiǎn),特別是對(duì)于穿刺飾品風(fēng)險(xiǎn)更大

    Abstract:

    Nickel is widely used as a bleaching element in white gold alloys for jewelry, it helps to obtain good color and mechanical properties. Although master alloy suppliers promise the safety of their products, the nickel allergy cases caused by such white gold jewelries are reported now and then. The purpose of this study is to investigate nickel release rate of a so-called “No nickel allergy” 10 K white gold alloy extensively used for jewelry and its potential risk to cause nickel allergy. The samples were processed by different heat treatment conditions and surface treatment methods, their nickel release rate were tested according to EN1811 standard. The results show that nickel release rate is closely related to the corrosion resistance and changes under different processing conditions even for the same material. The nickel release rate sequence (from big to little) is as follows: “annealing at the two-phase region with rough surface > cold working with rough surface > cold working with polishing surface > quenching with rough surface > quenching plus low temperature tempering with rough surface”. Although the adjusted values of nickel release rate under various process conditions met the requirement in nickel Directive “94/27/EC”, most of them fail to meet the requirement specified in “2004/96/EC” for piercing jewelry, and the actual values obviously markedly exceed both Directives. There would exist nickel allergy risk for jewelries made from this material, especially for puncture accessories

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袁軍平,李 衛(wèi),王 昶. Nickel Release of 10 K White Gold Alloy for Jewelry[J].稀有金屬材料與工程,2012,41(6):947~951.[Yuan Junping, Li Wei, Wang Chang. Nickel Release of 10 K White Gold Alloy for Jewelry[J]. Rare Metal Materials and Engineering,2012,41(6):947~951.]
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  • 收稿日期:2011-07-29
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