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1-乙基-3-甲基-咪唑四氟硼酸鹽離子液體中鏑電沉積行為
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中央高?;究蒲袠I(yè)務(wù)費(fèi)專(zhuān)項(xiàng)資金(N100302008)


Electrodeposition Behavior of Dysprosium in EMIMBF4 Ionic Liquid
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    摘要:

    研究室溫下Pt電極上Dy3+離子在1-乙基-3-甲基-咪唑四氟硼酸鹽 (EMIMBF4) 離子液體中的電化學(xué)行為。循環(huán)伏安法結(jié)合計(jì)時(shí)電流法和計(jì)時(shí)電位法研究結(jié)果表明,Dy3+離子的電化學(xué)還原是不可逆過(guò)程,還原為一步完成,即Dy3++3e-→Dy。計(jì)時(shí)電流法結(jié)合恒電位電解研究表明,Dy3+離子的還原過(guò)程受擴(kuò)散控制。測(cè)得濃度0.01 mol/L的 Dy3+離子在0.1 mol/L LiCl-EMIMBF4離子液體中的傳遞系數(shù)、擴(kuò)散系數(shù)分別為0.176和 (4.87-5.04)×10-10 cm2/s。SEM和XRD分析表明,金屬鏑顆粒直徑為幾百納米。

    Abstract:

    The electrodeposition of dysprosium on a Pt electrode from 1-ethyl-3-methyl-imidazolium tetrafluoroborate (EMIMBF4) ionic liquid was investigated. The cyclic voltammetry, chronopotentiometry and chronoamperometry were employed to examine the electrochemistry of Dy3+ in 0.01 mol/L DyCl3-0.1 mol/L LiCl-EMIMBF4 ionic liquid. The electrochemistry experiments indicate that the reduction of Dy3+ ion in 0.01 mol/L DyCl3-0.1 mol/L LiCl-EMIMBF4 ionic liquid is an irreversible process and is completed through only one step electrodeposition mechanism Dy3+ + 3e-→Dy. In 0.01 mol/L DyCl3-0.1 mol/L LiCl-EMIMBF4 ionic liquid the transfer coefficient and the diffusion coefficient of Dy3+ ion have been determined to be 0.176 and (4.87-5.04)×10-10 cm2/s, respectively. XRD pattern shows that the dysprosium deposits can be obtained, and SEM images shows that crystallites sizes of the deposits are few hundred nanometers.

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金炳勛,謝宏偉,毛 景,翟玉春.1-乙基-3-甲基-咪唑四氟硼酸鹽離子液體中鏑電沉積行為[J].稀有金屬材料與工程,2012,41(5):881~884.[Kim Pyonghun, Xie Hongwei, Mao Jing, Zhai Yuchun. Electrodeposition Behavior of Dysprosium in EMIMBF4 Ionic Liquid[J]. Rare Metal Materials and Engineering,2012,41(5):881~884.]
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  • 收稿日期:2011-05-31
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