方向聚集形成樹突,銀納米顆粒是3×{422}位面;相應的,當濃度達到1 mol/L 時,形成的納米顆粒在沿著<211>方向聚集的同時,在<110>方向形成第2個聚集單位,并最終形成多空的盤狀結(jié)構(gòu)的介觀晶體,其厚度約為50 nm ;當濃度為2 mol/L時,納米顆粒繼續(xù)沿著<110>方向聚集,形成三角形的板狀結(jié)構(gòu),隨著聚集的越來越多,最終形成厚度超過100 nm 的單晶介觀晶體"/>

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Insight into the Mechanism of Nanoparticle-Aggregated Crystallization for Mesocrystals
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Insight into the Mechanism of Nanoparticle-Aggregated Crystallization for Mesocrystals
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National Science Foundation of China (50824001, 50771077, 50871080)

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    摘要:

    研究和探討了銀介觀晶體的形成過程和機理,銀介觀晶體通過AgNO3溶液和Sn替換反應合成原始的納米微粒。在200 mmol/L 濃度下,納米顆粒沿著<211>方向聚集形成樹突,銀納米顆粒是3×{422}位面;相應的,當濃度達到1 mol/L 時,形成的納米顆粒在沿著<211>方向聚集的同時,在<110>方向形成第2個聚集單位,并最終形成多空的盤狀結(jié)構(gòu)的介觀晶體,其厚度約為50 nm ;當濃度為2 mol/L時,納米顆粒繼續(xù)沿著<110>方向聚集,形成三角形的板狀結(jié)構(gòu),隨著聚集的越來越多,最終形成厚度超過100 nm 的單晶介觀晶體

    Abstract:

    silver mesocrystals have been synthesized via oriented attachment of primary building nanoparticles in simple and fast replacement reactions between AgNO3 solution and Sn. The formation process of silver mesocrystals is discussed in detail and the growth mechanism is suggested to describe the formation of silver mesocrystals. In a 200 mmol/L solution, the primary nanoparticles orientationally aggregate along <211> directions to form a dendrite, the proposed attachment planes and directions for Ag nanoparticles are 3×{422} planes and <211> directions, respectively. When the concentration increases to 1 mol/L, the primary building nanoparticles orientotionally aggregate along <211> directions to form dendrites. The dendrites that can be proposed as the second building units orientationally attach along <110> directions to construct a porous monocrystalline plate, and finally transit to a mesocrystal with a thickness about 50 nm. When the AgNO3 concentration is 2 mol/L, the building units are Ag triangle platelets. These platelets also orientationally attach along <110> directions to form a monocrystalline dense plate and finally the plate transforms to monocrystalline mesocrystal with a thickness over 100 nm

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商洪濤,于淑湘,林 媛,張 銘,朱 超,何文喜,周澤淵. Insight into the Mechanism of Nanoparticle-Aggregated Crystallization for Mesocrystals[J].稀有金屬材料與工程,2012,41(4):589~593.[Shang Hongtao, Yu Shuxiang, Lin Yuan, Zhang Ming, Zhu Chao, He Wenxi, Zhou Zeyuan. Insight into the Mechanism of Nanoparticle-Aggregated Crystallization for Mesocrystals[J]. Rare Metal Materials and Engineering,2012,41(4):589~593.]
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  • 收稿日期:2011-03-25
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