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Effects of C10H8 Doping on Microstructure and Superconductivity of MgB2 Wires
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Effects of C10H8 Doping on Microstructure and Superconductivity of MgB2 Wires
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“863” Project (2007AA03Z237),the National Key Basic Research Program (No. 2011CBA00104) of China

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    摘要:

    采用原位粉末裝管技術(shù)(in-situ PIT)制備了萘(C10H8)摻雜MgB2/Nb/Cu線材。前驅(qū)粉末按照MgB2+xwt% (x=0,2,5,8)的比例將Mg粉、B粉和C10H8粉末混合研磨,裝入Cu/Nb復(fù)合管中,分別拉拔加工至Φ2.0 mm和Φ1.0 mm,然后Ar氣氛中分別在650,700,750 ℃熱處理,保溫2.5 h。通過X射線衍射儀(XRD)、掃描電子顯微鏡(SEM)和能譜儀(EDS)等測試手段分析了樣品的相結(jié)構(gòu)和微觀結(jié)構(gòu)等。結(jié)果發(fā)現(xiàn),樣品超導(dǎo)轉(zhuǎn)變溫度Tc不隨萘摻雜量的變化而變化,但正常態(tài)電阻有所降低。在20和25 K無外磁場時,x=8樣品的臨界電流密度分別達到1.1×105和3.8×104 A/cm2,而x=5樣品也達到3.1×104 和 1.2×104 A/cm2。

    Abstract:

    C10H8-doped MgB2 wires were fabricated by in-situ PIT (Powder in Tube) method. The Nb/Cu tube was filled with the uniformly mixed precursor powders of magnesium, boron and C10H8 with the stoichiometry of MgB2+xwt%C10H8 ,where x=0, 2, 5, 8 and drawn to diameter Φ2 mm and Φ1 mm, respectively, and then heat treated in argon atmosphere at three different temperatures (650, 700, 750 ℃) for 2.5 h. The phase formation and microstructures of the samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), and so on. It is found that the critical transition temperature (Tc) changes little with increasing of C10H8 doping content, while normal resistance decreases to some degree. At 20, 25 K and in zero external field, the critical current density (Jc) the sample of x=8 achieves 1.1×105 and 3.8×104 A/cm2, respectively, and the Jc of the sample of x=5 reaches 3.1×104 and 1.2×104 A/cm2, respectively.

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孫昱艷,張平祥,熊曉梅,劉國慶,閆 果. Effects of C10H8 Doping on Microstructure and Superconductivity of MgB2 Wires[J].稀有金屬材料與工程,2012,41(1):5~8.[Sun Yuyan, Zhang Pingxiang, Xiong Xiaomei, Liu Guoqing, Yan Guo. Effects of C10H8 Doping on Microstructure and Superconductivity of MgB2 Wires[J]. Rare Metal Materials and Engineering,2012,41(1):5~8.]
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  • 收稿日期:2011-01-11
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