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正向電壓對鎂合金微弧氧化膜層相結(jié)構(gòu)的影響
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國家自然科學(xué)基金項目(51072057, 50902052, 50872035)


Effect of Positive Voltage on Phase Structure of Micro-arc Oxidation Films of Magnesium Alloy
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    摘要:

    采用微弧氧化技術(shù),以30 g/L的磷酸鈉為電解液,利用系統(tǒng)的XRD手段研究了正向電壓對AZ31鎂合金表面微弧氧化膜層不同厚度的相組成,計算出晶粒尺寸、晶面間距和殘余應(yīng)力的分布規(guī)律。結(jié)果表明:電壓不同膜層中各深度相的衍射峰強度、相組成和結(jié)晶度都不同,其中Mg3(PO4)2 (200)峰的晶粒尺寸隨電壓增加而變粗,且同一電壓制備的膜層在同一晶向不同厚度的晶粒尺寸不一樣,其值呈至膜層表面距離減小而減小,晶面間距也呈減小趨勢;MgO相組成的涂層殘余應(yīng)力處于拉應(yīng)力,其值隨電壓增加而顯著減小。

    Abstract:

    The composite coatings on AZ31 magnesium alloy substrate were prepared by micro-arc oxidation (MAO) technique in sodium phosphate electrolyte. The effects of positive voltage on phase composition of different-thickness MAO films were investigated. Grain size, d-spacing and residual stresses were calculated based on systematical XRD class study. Results reveal that the diffraction peak intensity, phases and crystallinity of different-depth are different and the grain size of Mg3(PO4)2 (200) peak becomes bigger with increasing the positive voltage. Even preparing the film under the same voltage, the grain sizes of the same crystal orientation at different depths are still different, decreasing with reducing the depth from the surface of thin films, while the d-spacing has the same tendency. Residual stresses attributed to the MgO constituent of the coatings were calculated to be tensile. With the increase of the applied voltages, stress values are decreased sharply.

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熊文名,寧成云,顧艷紅,張 京.正向電壓對鎂合金微弧氧化膜層相結(jié)構(gòu)的影響[J].稀有金屬材料與工程,2011,40(12):2236~2240.[Xiong Wenming, Ning Chengyun, Gu Yanhong, Zhang Jing. Effect of Positive Voltage on Phase Structure of Micro-arc Oxidation Films of Magnesium Alloy[J]. Rare Metal Materials and Engineering,2011,40(12):2236~2240.]
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  • 收稿日期:2010-10-24
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