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Synthesis of Silver Nanoplates without Agitation andSurfactant
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Synthesis of Silver Nanoplates without Agitation andSurfactant
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Jiangsu Province College Natural Science Foundation (08KJD150003); Young Foundation of Changzhou (CQ2008011); Open Foundation of Jiangsu Key Laboratory of Precious Metals Chemistry (SYGK0709); Application Basis Research Program of Jiangsu Teachers University of Technology (KYY08001)

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    摘要:

    在液相體系中成功制備了單分散的銀納米片,反應(yīng)過程中沒有機(jī)械攪拌及使用任何表面活性劑,只用硝酸銀和維生素C作為原料。相反,使用機(jī)械攪拌,獲得的產(chǎn)物為銀的納米粒子團(tuán)聚體。產(chǎn)物的形貌和相結(jié)構(gòu)用掃描電子顯微鏡(SEM)、透射電子顯微鏡(TEM)和X射線粉末衍射(XRD)進(jìn)行了表征。討論了可能的反應(yīng)機(jī)理,有助于理解化學(xué)反應(yīng)過程中的粒子團(tuán)聚機(jī)理。

    Abstract:

    Dispersed silver nanoplates were prepared using silver nitrate and vitamin C in absence of agitation and surfactants in aqueous solution. In contrast, aggregated silver nanoparticles were obtained under mechanical agitation. The morphology and phases of products were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffractometer (XRD). The results show that the dispersed silver nanoplates can be obtained under the conditions of no mechanical agitation and no surfactants. The shear will induce the formation of aggregation.

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關(guān)明云,尚通明,賀香紅,孫建華,周全法,顧 鵬. Synthesis of Silver Nanoplates without Agitation andSurfactant[J].稀有金屬材料與工程,2011,40(12):2069~2071.[Guan Mingyun, Shang Tongming, He Xianghong, Sun Jianhua, Zhou Quanfa, Gu Peng. Synthesis of Silver Nanoplates without Agitation andSurfactant[J]. Rare Metal Materials and Engineering,2011,40(12):2069~2071.]
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  • 收稿日期:2010-12-26
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