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反相微乳液中納米金的可控合成及其機理研究
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國家自然科學基金(20673059和20573056);教育部重點項目(WK0913002)


Controlled Synthesis and Mechanism of Gold Nanoparicles in Reverse Microemulsions
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    摘要:

    在AOT/正庚烷/氯金酸反相微乳液中,用水合肼作為還原劑制備了納米金粒子, 用紫外-可見光譜和透射電鏡進行分析,系統(tǒng)地研究了水和表面活性劑摩爾比 (ω=nH2O/nAOT)以及氯金酸濃度對粒徑的影響。結果表明, 制備的納米金粒子粒徑在4~12 nm、單分散性好。納米金粒徑與ω值存在線性關系。氯金酸的濃度對粒徑的影響比較復雜, 隨著濃度增大, 粒徑先減小后增大。用FT-IR紅外光譜解釋了AOT的磺酸基對納米金粒子表面有強烈的吸附作用,從而對合成的納米金粒子有著很強的保護作用

    Abstract:

    Gold nanoparticles were prepared in W/O microemulsions of AOT/heptane/HAuCl4·3H2O system using N2H4·H2O as the reducing regent. These particles were characterized by UV-vis spectrum, TEM and FT-IR. The influences of the molar ratio of water to surfactant (ω=nH2O/nAOT) and the concentration of tetrachloroauric acid on the particle size were investigated. The results show that the average particle size of the prepared gold nanoparticles is from 4 nm to 12 nm, and their distribution is narrow. The relation between ω and average particles size is linearity. On the other hand, the influence of tetrachloroauric acid concentration is complex. As the concentration increases, the particle size decreases firstly and increases subsequently. FT-IR spectra indicate that the surfactant molecules are strongly absorbed on the surface of gold nanoparticles through a coordination bond between the gold atom and the sulfonic group of AOT molecules, so the surfactant AOT has a good protection effect.

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張 帆,齊文杰,安學勤,朱銀燕.反相微乳液中納米金的可控合成及其機理研究[J].稀有金屬材料與工程,2011,40(11):2055~2059.[Zhang Fan, Qi Wenjie, An Xueqin, Zhu Yinyan. Controlled Synthesis and Mechanism of Gold Nanoparicles in Reverse Microemulsions[J]. Rare Metal Materials and Engineering,2011,40(11):2055~2059.]
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  • 收稿日期:2010-11-22
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