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快淬速度對Nd10Fe81Co3B6薄帶微結(jié)構(gòu)及磁性能的影響
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河北省自然科學(xué)基金(E2010000125);國家教育部博士點(diǎn)基金(2007008004);天津市應(yīng)用基礎(chǔ)與前沿技術(shù)研究計(jì)劃重點(diǎn)項(xiàng)目(09JCZDJC22800)


Effects of Melt-Spinning Speed on Microstructure and Magnetic Properties of Nd10Fe81Co3B6 Ribbons
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    摘要:

    研究了快淬速度對熔體快淬法制備Nd10Fe81Co3B6薄帶微結(jié)構(gòu)及磁性能的影響。結(jié)果表明,隨著快淬速度的增加,薄帶中非晶相含量增加??齑惚г?00 ℃晶化處理10 min后,15 m/s淬速的薄帶基本由粒徑大于50 nm的Nd2(Fe,Co)14B與粒徑小于25 nm的Fe7Co3相組成,兩相交換耦合作用較弱,而50 m/s淬速的薄帶中仍含有大量的非晶相,使得薄帶的剩磁減小,但矯頑力沒有明顯降低;35 m/s淬速的薄帶退火后晶化完好,兩相交換耦合作用最好,矯頑力達(dá)到249 928 A/m,剩磁達(dá)到84.3 A·m2/kg。不同快淬速度薄帶中主相Nd2(Fe,Co)14B的居里溫度基本相同,約為630 K。

    Abstract:

    Nd10Fe81Co3B ribbons were prepared by melt-spinning method at different melt-spinning speeds, and the effects of melt-spinning speeds on the microstructure and magnetic properties of Nd10Fe81Co3B ribbons were studied. The results show that the content of amorphous phase is increased with increasing the melt-spinning speed. After annealed at 800 °C for 10 min, the ribbons melt-spun at 15 m/s speeds are consisted of Nd2(Fe,Co)14B and Fe7Co3. The medium grain size of Nd2(Fe,Co)14B is greater than 50 nm, however that of Fe7Co3 size is smaller than 25 nm. Inter-grains exchange coupling interaction is weakened; there are high content of amorphous phase in the ribbons melt-spun at 50 m/s, which makes the remanence reduce, and the coercivity didn’t obviously reduce. The ribbons melt-spun at 50 m/s had a optimum crystallization, and the inter-grains exchange coupling interaction acted well. Their magnetic properties are Hc=249 928 A/m, Mr=84.3 A·m2/kg. Furthermore, Curie temperature of the ribbons with different melt-spinning speeds are basically same, it’s about 630 K.

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韓瑞平,崔春翔,孫繼兵,楊 薇.快淬速度對Nd10Fe81Co3B6薄帶微結(jié)構(gòu)及磁性能的影響[J].稀有金屬材料與工程,2011,40(10):1852~1854.[Han Ruiping, Cui Chunxiang, Sun Jibing, Yang Wei. Effects of Melt-Spinning Speed on Microstructure and Magnetic Properties of Nd10Fe81Co3B6 Ribbons[J]. Rare Metal Materials and Engineering,2011,40(10):1852~1854.]
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  • 收稿日期:2010-10-26
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