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溶膠-噴霧干燥超細(xì)/納米晶W-20Cu復(fù)合粉末的燒結(jié)行為
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國家杰出青年科學(xué)基金(50925416);國家自然科學(xué)基金(50874122);國家自然科學(xué)基金委員會(huì)創(chuàng)新研究群體科學(xué)基金(50721003)


Sintering Behavior of Ultrafine/Nanocrystalline W-20Cu Composite Powders Synthesized by Sol-Spray Drying
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    摘要:

    采用噴霧干燥-氫氣還原法制備超細(xì)/納米晶W-20Cu(質(zhì)量分?jǐn)?shù), %)復(fù)合粉末,粉末壓坯直接從室溫推入高溫區(qū)燒結(jié)不同時(shí)間后直接取出水淬,研究其燒結(jié)致密化和顯微組織的變化。結(jié)果表明,超細(xì)/納米晶W-20Cu粉末在1000 ~1200 ℃燒結(jié)時(shí)發(fā)生迅速致密化。粉末壓坯在1200 ℃燒結(jié)60 min,其材料致密度已達(dá)到96.4%。1420 ℃燒結(jié)90 min時(shí)致密度達(dá)到99%以上。1100~1420 ℃燒結(jié)時(shí)其燒結(jié)致密化活化能不斷減小,從1100 ℃時(shí)的276.3 kJ/mol減小到1420 ℃時(shí)的29.1 kJ/mol。當(dāng)溫度低于1200 ℃時(shí),W晶粒長(zhǎng)大不明顯,當(dāng)溫度超過1300 ℃時(shí),W晶粒開始有明顯長(zhǎng)大。隨溫度的升高W晶粒發(fā)生顯著球形化,1420 ℃燒結(jié)時(shí)發(fā)現(xiàn)其晶粒長(zhǎng)大符合G3=kt的Ostwald機(jī)制,此時(shí)晶粒長(zhǎng)大動(dòng)力學(xué)系數(shù)K僅為0.024 μm3/min

    Abstract:

    Ultrafine/nanocrystalline W-20Cu (mass fraction) composite powders were synthesized by sol-spray drying and subsequent hydrogen reduction process. The powders compacts were sintered at various sintering temperatures for different holding time and then were rapidly quenched in water. The sintering densification and microstructure evolution were investigated. The results show that significant densification occurs at the sintering temperature ranging from 1000 to 1200 oC and 96.4% theoretical density can be realized when sintered at 1200 oC for 60 min. When the sintering temperature is further elevated to 1420 oC and the holding time is 90 min, the relative density of the sintered compacts exceeds the level of 99%. In the range of 1100-1420 oC, the activation energy of sintering densification decreases with the sintering temperature increasing and the value decreases from 276.3 kJ/mol at 1100 oC to 29.1 kJ/mol at 1420 oC. There is no obvious grain growth during the sintering stage below 1200 oC, whereas the grain coarsening is very rapid when the sintering temperature is above 1300 oC. As the sintering temperature increasing, the tungsten grains become spherical. In addition, the grain coarsening at the temperature of 1420 oC is in good agreement with the Ostwald mechanism and the grain coarsening kinetic coefficient is 0.024 μm3/min

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范景蓮,朱 松,劉 濤,田家敏,龔 星.溶膠-噴霧干燥超細(xì)/納米晶W-20Cu復(fù)合粉末的燒結(jié)行為[J].稀有金屬材料與工程,2011,40(9):1643~1647.[Fan Jinglian, Zhu Song, Liu Tao, Tian Jiamin, Gong Xing. Sintering Behavior of Ultrafine/Nanocrystalline W-20Cu Composite Powders Synthesized by Sol-Spray Drying[J]. Rare Metal Materials and Engineering,2011,40(9):1643~1647.]
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  • 收稿日期:2010-09-10
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