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Electrochemical Properties and Reaction Mechanism of Ti-V Multiphase Alloy at High Temperature
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Electrochemical Properties and Reaction Mechanism of Ti-V Multiphase Alloy at High Temperature
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National Natural Science Foundation of China (50901030)

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    摘要:

    研究333 K時(shí)Ti0.17Zr0.08V0.35Cr0.1Ni0.3 合金的循環(huán)穩(wěn)定性和高溫倍率放電性能。333 K時(shí)，當(dāng)放電電流密度為60 mA/g時(shí)，Ti0.17Zr0.08V0.35Cr0.1Ni0.3合金第1次放電容量為450 mAh/g。隨著充放電循環(huán)的進(jìn)行，放電容量迅速降低。當(dāng)放電電流密度為2400 mA/g，截止電壓為0.6 V時(shí)，Ti0.17Zr0.08V0.35Cr0.1Ni0.3合金的放電容量仍達(dá)到160 mAh/g。并詳細(xì)探討影響以上合金電化學(xué)性能的因素

    Abstract:

    The cyclic stability and the high-rate discharge characteristic of Ti0.17Zr0.08V0.35Cr0.1Ni0.3 alloy at 333 K were investigated. The results show that the discharge capacity of Ti0.17Zr0.08V0.35Cr0.1Ni0.3 alloy is ~450 mAh/g at a current density of 60 mA/g at 333 K for the first cycle, and then it obviously decreases with increasing of cycle number. It should be noted that the excellent discharge capacity of Ti0.17Zr0.08V0.35Cr0.1Ni0.3 alloy will remain 160 mAh/g at a current density of 2400 mA/g to cut-off voltage of 0.6 V. Moreover, the possible factors affecting the electrochemical performance of this alloy were discussed

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王 寧,柴玉俊. Electrochemical Properties and Reaction Mechanism of Ti-V Multiphase Alloy at High Temperature[J].稀有金屬材料與工程,2011,40(9):1519~1521.[Wang Ning, Chai Yujun. Electrochemical Properties and Reaction Mechanism of Ti-V Multiphase Alloy at High Temperature[J]. Rare Metal Materials and Engineering,2011,40(9):1519~1521.]
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  • 收稿日期:2010-09-20
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