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Ca含量對AZ61-1.2Y鎂合金耐蝕性能的影響
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河南省杰出人才計劃(084200510018);洛陽市科技發(fā)展計劃項目(0602018A);河南科技大學(xué)重大預(yù)研專項(2007ZD002)


Effect of Calcium Content on Corrosion Resistance of AZ61-1.2Y Magnesium Alloys
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    摘要:

    利用靜態(tài)失重法研究了不同Ca含量對AZ61-1.2Y鎂合金腐蝕速率的影響。用金相顯微鏡、掃描電子顯微鏡觀察試樣的微觀組織、表面腐蝕形貌。結(jié)果表明,添加1%的Ca(質(zhì)量分?jǐn)?shù),下同)時,合金的晶粒得到了明顯的細(xì)化,組織和成分更加均勻;當(dāng)Ca含量大于1%時,合金的析出相增多,并產(chǎn)生粗化、偏聚的現(xiàn)象。在兩種濃度的腐蝕介質(zhì)中(0.5%和3.5%的NaCl水溶液),合金的腐蝕速率均隨著Ca含量的增加呈現(xiàn)先減小后增大的趨勢,其中當(dāng)Ca含量為1%時合金的腐蝕速率均達(dá)到最低,耐蝕性能得到明顯的改善。

    Abstract:

    Effect of calcium content on corrosion rate of AZ61-1.2Y magnesium alloys in 0.5% and 3.5% NaCl solution was studied by the static mass-loss tests. The microstructures of the alloys were observed by optical microscope and the morphologies of corrosion surface were analyzed with scanning electron microscopy. The results indicate that with the addition of 1wt% calcium, the grain size of the AZ61-1.2Y alloys is obviously refined, and the microstructure and component is more homogeneous. But when the addition of calcium is more than 1wt%, the precipitates of the alloys increase and they cause the phenomenon of coarsening and segregation. Furthermore, in 0.5% and 3.5% NaCl solution, the corrosion rates of the alloys decrease firstly and then increase with the increase of calcium content. With the addition of 1wt% calcium, the corrosion rate of the alloys is lowest, and the corrosion resistance is improved remarkably.

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李肖豐,李全安,陳 君,張 清,張興淵. Ca含量對AZ61-1.2Y鎂合金耐蝕性能的影響[J].稀有金屬材料與工程,2011,40(8):1466~1469.[Li Xiaofeng, Li Quan’an, Chen Jun, Zhang Qing, Zhang Xingyuan. Effect of Calcium Content on Corrosion Resistance of AZ61-1.2Y Magnesium Alloys[J]. Rare Metal Materials and Engineering,2011,40(8):1466~1469.]
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  • 收稿日期:2010-08-30
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