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鍶、釹對Mg-9Al-1Si-0.3Zn合金微觀組織和力學(xué)性能的影響
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國家高技術(shù)研究發(fā)展計劃(“863”計劃)(2009AA03Z114);清華-東洋鎂鋁合金成型技術(shù)研究開發(fā)中心項目


Effects of Sr and Nd Addition on Microstructure and Mechanical Properties of Mg-9Al-1Si-0.3Zn Alloy
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    摘要:

    當鎂合金中添加含量較高的Si時,會形成大量粗大漢字狀的Mg2Si,嚴重影響合金的力學(xué)性能。通過Sr和Nd及其復(fù)合添加細化Mg-9Al-1Si-0.3Zn合金中粗大的Mg2Si,研究添加元素對合金微觀組織和室溫力學(xué)性能的影響,分析了Sr和Nd對Mg2Si的細化機制。結(jié)果表明,隨著Sr的加入,漢字狀Mg2Si的形貌得到改善,形成了均勻的多邊形塊狀;當Sr添加到0.16%(質(zhì)量分數(shù),下同)時,Mg2Si得到了完全的細化。當同時添加Nd和Sr元素時,合金中出現(xiàn)新的以Mg,Al,Nd和Si形成的物相;隨著Nd的增加,這種新的物相增多,這種化合物提供了Mg2Si相細化的異質(zhì)核心。在Sr和Nd的復(fù)合作用下,漢字狀Mg2Si被細化,合金的力學(xué)性能得到改善。

    Abstract:

    A large amount of coarse Chinese-script-like Mg2Si particles in the magnesium alloys containing much silicon is harmful to the mechanical properties of the alloys. Sr and Nd were added in Mg-9Al-1Si-0.3Zn alloy to refine the coarse Mg2Si, and the effect of the added elements on microstructures and mechanical properties of the alloy were studied. The refining mechanism of Sr and Nd to Mg2Si was analyzed. The results show that the Chinese-script-like morphology of the Mg2Si particles is improved and uniform polygonal block are formed with the addition of Sr element. When the Sr addition is 0.16 wt%, the particles appear in a completely polygonal morphology. When both Sr and Nd elements are added to the alloy, an intermetallic compound of Mg, Al, Nd and Si elements precipitate; the more added Nd, the more new phases, which act as the heterogeneous nuclei for the growth of the Mg2Si particles. The Mg2Si particles are refined as an irregular shape under the combination effects of Sr and Nd elements. The grain-refinement on Mg2Si particles improves the mechanical properties of the alloy.

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鄒志文,熊守美.鍶、釹對Mg-9Al-1Si-0.3Zn合金微觀組織和力學(xué)性能的影響[J].稀有金屬材料與工程,2011,40(8):1402~1406.[Zou Zhiwen, Xiong Shoumei. Effects of Sr and Nd Addition on Microstructure and Mechanical Properties of Mg-9Al-1Si-0.3Zn Alloy[J]. Rare Metal Materials and Engineering,2011,40(8):1402~1406.]
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  • 收稿日期:2010-08-22
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