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FGH95粉末冶金高溫合金長(zhǎng)期時(shí)效的組織穩(wěn)定性
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Microstructure Stability of FGH95 P/M Superalloy after Long-Term Aging
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    摘要:

    利用掃描電鏡和透射電鏡觀察了FGH95鎳基粉末冶金高溫合金在650 ℃長(zhǎng)期時(shí)效后的顯微結(jié)構(gòu),評(píng)價(jià)了該合金在時(shí)效過(guò)程中的組織穩(wěn)定性。結(jié)果表明,該合金在650 ℃具有較好的組織穩(wěn)定性。經(jīng)500~5000 h時(shí)效后,合金的主要析出相為γ′相、MC型和M23C6型碳化物,在合金中沒(méi)有發(fā)現(xiàn)TCP相。γ′相在不同熱處理時(shí)期具有3種不同的尺寸及形貌:尺寸為1~3 μm的γ′相,呈不規(guī)則塊狀在晶界析出;尺寸約為500 nm的γ′相,呈蝶形均勻分布于基體中,隨時(shí)效時(shí)間延長(zhǎng),其大小、形貌及在基體中的分布稍有變化;更小的γ′相在長(zhǎng)期時(shí)效過(guò)程中經(jīng)歷不規(guī)則長(zhǎng)大、分裂、再長(zhǎng)大和再分裂的循環(huán)過(guò)程,尺寸在60~200 nm范圍內(nèi)變化。合金時(shí)效3000 h時(shí)發(fā)現(xiàn)晶界上生成M23C6型碳化物。

    Abstract:

    The microstructure of a Ni-based P/M superalloy FGH95 after long-term aging at 650 oC was observed by SEM and TEM and its microstructure stability was also investigated. The results show that the microstructure of the alloy is stable at 650 oC. The major precipitated phases of the alloy are γ′ phase and carbides of MC and M23C6 without TCP phase precipitating after aging for 500-5000 h. The γ′ phase is precipitated in the matrix in three kinds of sizes during different heat treatment processes. The size of bulk γ′ phase is about 1 to 3 μm, which is precipitated on grain boundary. The size of intragranular γ′ phase is about 500 nm, with the shape of butterfly, which changes a little in size, morphology and distribution in matrix during the aging process. And the smaller γ′ phase experiences a series of changes such as growing up, splitting and growing up again and splitting again in long-term aging. Its size is in a range of 60 to 200 nm. A kind of carbide M23C6 is found on the grain boundary in the alloy aged for 3000 h.

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席文君,邢 潔,張義文. FGH95粉末冶金高溫合金長(zhǎng)期時(shí)效的組織穩(wěn)定性[J].稀有金屬材料與工程,2011,40(8):1397~1401.[Xi Wenjun, Xing Jie, Zhang Yiwen. Microstructure Stability of FGH95 P/M Superalloy after Long-Term Aging[J]. Rare Metal Materials and Engineering,2011,40(8):1397~1401.]
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  • 收稿日期:2010-08-24
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