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Y2O3摻雜ZrB2-SiC基超高溫陶瓷的抗燒蝕性能
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國(guó)家自然科學(xué)基金項(xiàng)目(50602010, 50702016); 國(guó)防預(yù)研基金(BAQQ24402052); 博士后基金(BAQQ24403037)


Ablation Resistance Behavior of ZrB2-SiC Ultra-High Temperature Ceramics with Y2O3 Addition
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    摘要:

    為改善ZrB2-SiC基超高溫陶瓷的抗氧化和抗燒蝕性能,在制備過(guò)程中加入Y2O3。用氧乙炔火焰法來(lái)考察ZrB2-SiC-Y2O3的抗氧化和抗燒蝕性能。采用SEM和XRD分析燒蝕前后形貌及物相。材料在加熱和冷卻過(guò)程中沒(méi)有出現(xiàn)開裂現(xiàn)象,說(shuō)明其具有良好的抗熱沖擊性能。微觀組織分析表明,氧化層主要由4層組成,且氧化層與基體層沒(méi)有明顯的剝離。結(jié)果表明:Y2O3的添加可以將氧化產(chǎn)物中的高溫穩(wěn)定相穩(wěn)定到室溫,減少由于相變發(fā)生的體積膨脹,改善氧化層與基體層的粘結(jié)性能

    Abstract:

    In order to improve the oxidation resistance and ablation resistance of ZrB2-SiC ultra-high temperature ceramics (UHTCs), Y2O3 particles were introduced during the fabrication process of the ZrB2 based UHTCs. The oxidation-resistance and ablation-resistance of ZrB2-SiC-Y2O3 UHTCs were investigated using oxyacetylene torch test. The microstructures and phases of ZrB2-SiC-Y2O3 before and after ablation were studied by SEM and XRD. No cracks are found on the ablated surface during the process of heating and cooling, indicating that ZrB2-SiC-Y2O3 UHTCs have good thermal shock resistance. Microstructure analysis shows that the oxidation layer is composed of 4 layers and there is no obvious exfoliation between the oxidation layer and the substrate layer. The results show that high temperature stable phase t-ZrO2 in the oxidation product can be kept at low temperature by the addition of Y2O3, thus reducing the volume expansion owing to transformation and improving coherent properties of oxidation layers

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李學(xué)英,張幸紅,韓杰才,韓文波,洪常青. Y2O3摻雜ZrB2-SiC基超高溫陶瓷的抗燒蝕性能[J].稀有金屬材料與工程,2011,40(5):820~823.[Li Xueying, Zhang Xinghong, Han Jiecai, Han Wenbo, Hong Changqing. Ablation Resistance Behavior of ZrB2-SiC Ultra-High Temperature Ceramics with Y2O3 Addition[J]. Rare Metal Materials and Engineering,2011,40(5):820~823.]
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  • 收稿日期:2010-05-13
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