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冷卻速率對(Bi,Pb)-2223/Ag超導帶材微觀結構和性能的影響
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Effects of the Cooling Rate on the Microstructure and Properties of (Bi,Pb)-2223/Ag Tapes
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    摘要:

    研究了(Bi,Pb)-2223/Ag帶材在第1次熱處理后,不同的冷卻速率對其輸運性能和微觀結構的影響。利用XRD、SEM等分析手段對樣品進行表征。結果表明:隨著冷卻速率的降低,帶材中的2201相不斷減少直至消失,而Ca2PbO4相的含量卻不斷增加;與此同時,帶材中第二相粒子的尺寸也不斷增大。帶材的輸運電流測量表明,隨冷卻速率(對數坐標)的降低,樣品的臨界電流密度線性增加,同時,帶材在磁場下的性能也不斷提高。這是由于慢冷導致(Bi,Pb)-2223/Ag帶材的晶粒連接性變好和磁通釘扎能力提高造成的。

    Abstract:

    The influence of cooling rates on the microstructure and transport properties of (Bi,Pb)-2223/Ag tapes after the first heat treatment was investigated. The samples were characterized by XRD and SEM. Results show that the 2201 phases decrease until disappear while Ca2PbO4 increases continuously as the cooling rate decreases; at the same time the size of non-superconducting secondary phase particles become larger. The transport current tests show that the critical current density increases linearly with the cooling rate decreasing logarithmically; meanwhile, the transport current properties of the tapes in the magnetic field increases. This behavior is attributed to improvement of the grain connectivity and flux pinning properties of the tapes as the cooling rate is decreased.

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陳興品,余曉偉,李明亞,劉 慶,韓征和.冷卻速率對(Bi, Pb)-2223/Ag超導帶材微觀結構和性能的影響[J].稀有金屬材料與工程,2011,40(4):737~740.[Chen Xingpin, Yu Xiaowei, Li Mingya, Liu Qing, Han Zhenghe. Effects of the Cooling Rate on the Microstructure and Properties of (Bi, Pb)-2223/Ag Tapes[J]. Rare Metal Materials and Engineering,2011,40(4):737~740.]
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  • 收稿日期:2010-04-26
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