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噴射沉積Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd合金組織與力學(xué)性能研究
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內(nèi)蒙古自然科學(xué)基金(2009MS0807);內(nèi)蒙古科技攻關(guān)項(xiàng)目(20091502)


Microstructure and Mechanical Properties of Spray Deposited Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd Alloy
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    利用XRD、OM、SEM、TEM研究了噴射沉積Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd合金擠壓態(tài)的顯微組織和合金的力學(xué)性能。結(jié)果表明:噴射沉積擠壓態(tài)鎂合金主要包含基體α-Mg和Al2Ca相,基體組織為等軸晶,平均晶粒尺寸為3 μm;Al2Ca顆粒主要沿鎂基體晶界分布,顆粒尺寸在1.0 μm左右,并在Al2Ca相中存在孿晶結(jié)構(gòu);合金的σb、σ0.2、δ分別為450、325 MPa,5%。在拉伸斷口上存在大量石塊狀的Al2Ca相,表明合金的斷裂方式為沿晶斷裂;與經(jīng)熱擠壓的鑄造AZ91鎂合金對(duì)比,該合金強(qiáng)度明顯提高,但合金塑性降低;合金強(qiáng)度的提高主要來(lái)源于合金的細(xì)晶強(qiáng)化和Al、Zn對(duì)合金的固溶強(qiáng)化,而伸長(zhǎng)率降低是由于合金中存在的大量Al2Ca顆粒是沿鎂基體晶界分布,導(dǎo)致合金的塑性降低。

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    The microstructure and mechanical properties of a spray-deposited Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd alloy under the hot extrusion condition were studied by XRD, OM, SEM, TEM and tensile tester. The results show that the spray-deposited as-extruded Mg alloy mainly consists of α-Mg matrix and Al2Ca phases. The matrix structure is equiaxed grain and the average grain size is about 3 μm. The Al2Ca phases with the grain size of about 1.0 μm, mainly distribute along the boundaries of the Mg matrix; furthermore, the twin structures exist in the Al2Ca phase. The σb, σ0.2 and δ of the Mg alloy reach 450, 325 MPa and 5%, respectively. Fracture morphologies show the massive stone-like Al2Ca phases, and it is the characteristic of intergranular fracture mode. Compared with conventional cast AZ91 alloy after hot extrusion, the spray deposited Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd alloy possesses higher strength, but with poor ductility. High strength of the spray deposited Mg alloy is attributed to fine crystal strengthening and solution strengthening of Al and Zn atoms in the Mg matrix, while massive Al2Ca phases distributing along grain boundaries of the Mg matrix are responsible for the poor ductility in the Mg alloy.

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董太尚,白樸存,侯小虎,張秀云,陳 偉.噴射沉積Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd合金組織與力學(xué)性能研究[J].稀有金屬材料與工程,2011,40(4):689~692.[Dong Taishang, Bai Pucun, Hou Xiaohu, Zhang Xiuyun, Chen Wei. Microstructure and Mechanical Properties of Spray Deposited Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd Alloy[J]. Rare Metal Materials and Engineering,2011,40(4):689~692.]
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  • 收稿日期:2010-04-22
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