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電場激活原位合成(TiC)pNi/TiAl/Ti功能梯度材料
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國家自然科學(xué)基金(50671070,50975190)


In-Situ Synthesis of (TiC)pNi/TiAl/Ti Functional Gradient Materials via Field-Activated Process
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    摘要:

    運用電場激活壓力輔助合成(FAPAS)和原位合成技術(shù)制備了(TiC)pNi/TiAl/Ti功能梯度材料,研究了電場對材料合成及層界面擴(kuò)散連接的作用。采用光學(xué)顯微鏡、掃描電子顯微鏡、能譜和X射線衍射儀分析了梯度材料各層及界面微觀組織、相組成和元素分布。結(jié)果表明,電場的施加以及TiAl的燃燒反應(yīng)是合成材料的關(guān)鍵;經(jīng)原位合成的TiC顆粒均勻細(xì)?。唤饘偬沾蓪?TiAl/Ti基板的界面區(qū)產(chǎn)生了成分的互擴(kuò)散并形成了良好的冶金結(jié)合。鈦板到金屬陶瓷層的顯微硬度呈梯度變化且具有較好的抗熱震性。

    Abstract:

    (TiC)PNi/TiAl/Ti functional gradient materials (FGMs) were prepared by field-activated pressure-assisted synthesis ( FAPAS) and in-situ synthesis processes. The roles of the electric field in material synthesis and diffusion bonding of layers were investigated. The microstructure and phase composition of each layer as well as component distribution of elements across the interfaces of the layers were analyzed by means of OM, SEM, EDS and XRD. The results show that the imposition of the electric field and the combustion reaction of TiAl is the key for the successful synthesis of FGMs; the TiC particles formed by in-situ synthesis process are fine and distributed uniformly; moreover, concentration profiles of elements across the interfaces of the layers show significant inter-diffusion and good metallurgical bonding. The sample has an excellent thermal shock resistance ability and gradient distribution of micro-hardness across the titanium substrate to the surface layer.

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張 楠,陳少平,梁連杰,薛鵬飛,孟慶森.電場激活原位合成(TiC)pNi/TiAl/Ti功能梯度材料[J].稀有金屬材料與工程,2011,40(4):620~624.[Zhang Nan, Chen Shaoping, Liang Lianjie, Xue Pengfei, Meng Qingsen. In-Situ Synthesis of (TiC)pNi/TiAl/Ti Functional Gradient Materials via Field-Activated Process[J]. Rare Metal Materials and Engineering,2011,40(4):620~624.]
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  • 收稿日期:2010-04-22
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