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滑石粉化學鍍銀條件的探討
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浙江理工大學校啟動基金 (0601291-Y)


Study on the Electroless Silver Plating of Talcum Powder
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    摘要:

    以甲醛為還原劑,采用銀氨液滴入還原液的鍍液加入方式進行化學鍍銀法制備導電滑石粉,對滑石粉化學鍍銀條件進行了研究。探討了銀氨液pH值、硝酸銀濃度、甲醛濃度、粉體裝載量以及反應時間等因素對滑石粉化學鍍銀的影響規(guī)律。借助FESEM對鍍銀后滑石粉的表面形貌進行了表征,測試了化學鍍銀后滑石粉的增重率、壓實厘米電阻。在以上分析基礎(chǔ)上,得出滑石粉化學鍍銀的最佳工藝條件為:銀氨液pH值11.7,硝酸銀10 g/L,甲醛13 mL/L,裝載量25 g/L,反應時間60 min,得到的鍍銀滑石粉的厘米電阻為23.6 Ω×cm

    Abstract:

    Talcum powder has potential application in the field of conductive fillers preparation because of its particular structure. The conductive talcum powder was prepared by electroless silver plating with the way of silver ammonic solution dipping into the reduction solution with formaldehyde as reductant. The conditions of electroless silver plating for talcum powder were studied. Effects of pH value of the silver ammonic solution, concentration of the silver nitrate and formaldehyde, loadage of the powder and plating reaction time on the powder mass gain of coated silver were discussed. With the aid of FESEM, the morphology of talcum powder after silver plating was characterized; the rate of mass gain and the resistivity of the compacted talcum after silver-plating were tested. On the basis of the above analysis, the best conditions of electroless silver plating on talcum powder are drawn: pH value of silver ammonic solution 11.7, concentration of silver nitrate 10 g/L and that of formaldehyde 13 mL/L, loadage 25 g/L, and reaction time 60 min. Under these conditions, the resistivity of the compacted talcum powder after silver plating was 23.6 Ω×cm.

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裴付宇,陳建勇,張華鵬.滑石粉化學鍍銀條件的探討[J].稀有金屬材料與工程,2011,40(3):538~542.[Pei Fuyu, Chen Jianyong, Zhang Huapeng. Study on the Electroless Silver Plating of Talcum Powder[J]. Rare Metal Materials and Engineering,2011,40(3):538~542.]
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  • 收稿日期:2010-02-26
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