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鐵摻雜對(duì)鋁中氦行為的影響
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國家自然科學(xué)基金(50671017)


Effect of Iron Doping on Helium Behavior in Aluminum
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    摘要:

    通過離子注入技術(shù)在鋁中引入Fe、He兩元素,并采用X射線光電子能譜(XPS)、X射線衍射(XRD)、掃描電鏡(SEM)、透射電鏡(TEM)和熱氦脫附譜(THDS)研究Fe摻雜對(duì)鋁中離子注入氦行為的影響。結(jié)果表明,摻雜的Fe在鋁基體中主要以原子團(tuán)簇形式存在。預(yù)先摻雜的Fe原子對(duì)He+注入鋁的表面鼓泡和熱脫附行為有重要影響。且影響程度與摻雜Fe的劑量有關(guān):小劑量摻雜后,能有效抑制表面鼓泡現(xiàn)象,并使氣體釋放延遲;高劑量摻雜后,將加劇He+的注入損傷,出現(xiàn)剝落甚至重復(fù)剝落現(xiàn)象,同時(shí)使低溫區(qū)域氣體釋放增強(qiáng)。原因是,小劑量Fe摻雜后,鋁中形成了高He捕陷能力的第二相沉淀,抑制了氦泡的遷移和生長,從而影響了鋁中的微觀結(jié)構(gòu)演化和氣體釋放特性;高劑量Fe摻雜后,又會(huì)使這種抑制作用減弱。

    Abstract:

    Fe and He atoms were introduced into aluminum via ion implantation, and the effect of Fe-doping on the ion-implantation helium behavior in aluminum was studied by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and thermal helium desorption spectrometry (THDS). The results indicate that the doped Fe mainly exist in the form of atomic clusters in the matrix, and the behavior of surface blistering and thermal helium desorption has a close dependence on the doped-Fe and its dose. Small dose of Fe doping will result in effective resistance of surface blistering and delay of gas release, while large dose doping can deteriorate the irradiation damage, leading to flaking and even repeated flaking on the surface, and the enhancement of gas release in lower temperature range. The reasons are interpreted as following: when small dose of Fe are implanted in aluminum, second phase precipitates of high He trapping ability will form in the matrix, restraining the mobility and the growth of helium bubbles. Consequently, the microstructural evolution and gas release character are affected. However, the resistance effect will be weakened when large dose of Fe is doped in aluminum.

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向 鑫,劉柯釗,陳長安,劉婷婷,彭麗霞.鐵摻雜對(duì)鋁中氦行為的影響[J].稀有金屬材料與工程,2011,40(2):352~356.[Xiang Xin, Liu Kezhao, Chen Chang’an, Liu Tingting, Peng Lixia. Effect of Iron Doping on Helium Behavior in Aluminum[J]. Rare Metal Materials and Engineering,2011,40(2):352~356.]
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  • 收稿日期:2010-03-06
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