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導電纖維的制備及在防靜電陶瓷中的應用
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廣東省自然科學基金(05006564);廣東省科技攻關計劃項目(2004B10301007);廣西區(qū)教育廳基金(200808MS165)資助


Preparation of Conductive Fiber and Its Application in Antistatic Ceramics
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    摘要:

    以氧化硅玻璃纖維為載體,采用非均勻成核法在其表面包覆一層銻摻雜二氧化錫(ATO)制備了導電纖維。導電纖維的電阻率隨熱處理溫度升高的變化趨勢與ATO基本一致,包覆物加入率為100%、75%、50%、25%和12.5%的ATO包覆氧化硅纖維在500~1200 ℃處理后的電阻率全部低于200 Ω·cm。由于較大的長徑比所導致的橋聯(lián)效應,少量的導電纖維在陶瓷中就能形成完善的導電網絡,同時也能極大減少防靜電陶瓷中ATO的用量,包覆物加入率為12.5%的ATO包覆纖維作為導電填料時,能節(jié)省約77.8%的ATO。

    Abstract:

    Conductive fiber was prepared by coating antimony-doped tin oxide (ATO) on silicon dioxide glass fiber using a heterogeneous nucleation method. The varying trend of resistivity with the calcination temperature of the ATO-coated silicon dioxide fiber was almost the same as that of the pure ATO. The resistivities of the ATO-coated silicon dioxide fibers with the coating amounts of 100%, 75%, 50%, 25%, and 12.5% and treated at 500-1200 oC were all below 200 Ω·cm. As the conductive additive, the ATO-coated silicon dioxide fiber can maximally save the ATO amount because of the bridge effect resulting from its high aspect ratio, which makes it possible to form a more completed conductive net in the ceramics for a small quantity of conductive fibers. For instance, about 77.8% of ATO amount can be saved when the ATO-coated silicon dioxide fibers with 12.5% coating material are used as conductive filler.

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顏東亮,吳建青,陳 林.導電纖維的制備及在防靜電陶瓷中的應用[J].稀有金屬材料與工程,2010,39(11):2018~2022.[Yan Dongliang, Wu Jianqing, Chen Lin. Preparation of Conductive Fiber and Its Application in Antistatic Ceramics[J]. Rare Metal Materials and Engineering,2010,39(11):2018~2022.]
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  • 收稿日期:2009-12-21
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