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鎢基合金系擠壓喂料粘度與流變特性研究
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國家自然科學(xué)基金(50774098)


Research on Viscosity and Rheological Properties of Tungsten-Based Alloy PEM Feed
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    摘要:

    為了獲得有利于成形的粘結(jié)劑優(yōu)化配方,對相同粉末裝載量的4種粘結(jié)劑體系的93W-Ni-Fe 粉末増塑擠壓成形喂料粘度和流變行為進(jìn)行了研究。采用英國AR2000EX旋轉(zhuǎn)流變儀對鎢基合金系擠壓料在不同溫度、不同剪切速率下的粘度進(jìn)行測算。結(jié)果表明:對于不同粘結(jié)劑組成的喂料A、B、C和D中,A的粘度較低,流動性能較好,喂料D流變性能最不穩(wěn)定;根據(jù)剪切速率與粘度的關(guān)系曲線可測算出130 ℃時喂料A、B、C的剪切稀化指數(shù)分別為0.048,–0.869和–1.717;由溫度與粘度的關(guān)系曲線可測算出剪切速率為11.07 s-1時,喂料A、B、C的粘流活化能分別為8.524、8.107和31.310 kJ·mol-1;經(jīng)模擬計算可得在130 ℃和11.07 s-1速率下A、B、C 3種喂料的流動性指數(shù)分別為7.2×10-6,4.8×10-6, 1.1×10-6,A喂料的綜合流變學(xué)性能最好。

    Abstract:

    For an optimized formula of the cementing agent good for formation, the viscosity and rheological properties of 93W-Ni-Fe PEM feeds with the same powder loading but four kinds of binder composition systems which were called A, B, C and D feedstocks were studied. By the British AR2000EX rotary rheometer, the viscosity of the tungsten-based alloy PEM feed at different shear rates and different temperatures were measured. The results indicate that among the four feedstocks, A has a low viscosity and good flow properties. The rheological properties of D feed are the most unstable. According to their relationship curves between viscosity and shear rate at the 130 oC, the shear-thinning index of A, B and C feeds can be calculated as 0.048, –0.869 and –1.717, respectively. According to the relationship curves between viscosity and temperature at the shear-rate of 11.07 s-1, the flow activation energy of A, B and C feeds can be calculated as 8.524, 8.107 and 31.310 kJ·mol-1, respectively. Through simulation, at 130 oC and the shear-rate of 11.07 s-1, the liquidity index of A, B and C feeds is 7.2×10-6, 4.8×10-6 and 1.1×10-6, respectively. The comprehensive rheological performance of A feed is the best.

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馬運(yùn)柱,趙亞旭,劉文勝,張佳佳.鎢基合金系擠壓喂料粘度與流變特性研究[J].稀有金屬材料與工程,2010,39(11):1979~1983.[Ma Yunzhu, Zhao Yaxu, Liu Wensheng, Zhang Jiajia. Research on Viscosity and Rheological Properties of Tungsten-Based Alloy PEM Feed[J]. Rare Metal Materials and Engineering,2010,39(11):1979~1983.]
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  • 收稿日期:2010-06-08
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