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油溶性納米銅的制備及其在SF15W/40汽油機(jī)油中的摩擦學(xué)性能
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Synthesis and Tribological Behavior of Oil-Soluble Cu Nanoparticles as Additive in SF15W/40 Lubricating Oil
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National Natural Science Foundation of China (50575097); China Postdoctoral Science Foundation (20090461074)); Jiangsu Postdoctoral Science Foundation (0902007C); Start-up Foundation of Jiangsu University (08JDG049)

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    摘要:

    采用液相化學(xué)還原法結(jié)合界面生長(zhǎng)法,以醋酸銅為母體,維生素C (Vc)為還原劑,聚乙二醇2000為修飾劑,正丁醇為生長(zhǎng)劑,制得粒度分布為18.2~80.2 nm、平均粒度為44.7 nm的油溶性球形納米Cu樣品。XRD分析表明樣品的晶格常數(shù)膨脹率為1.478%。將樣品添加到SF15W/40汽油機(jī)油中制得金屬納米潤(rùn)滑油。高濃度激光粒度儀檢測(cè)表明,該金屬納米潤(rùn)滑油具有優(yōu)異的分散穩(wěn)定性。在UMT-Ⅱ摩擦磨損試驗(yàn)機(jī)上考察SF15W/40汽油機(jī)油、金屬納米潤(rùn)滑油的摩擦磨損性能。結(jié)果表明:與SF15W/40汽油機(jī)油相比,金屬納米潤(rùn)滑油較大程度降低了摩擦系數(shù),減小了磨損量,顯著改善了SF15W/40汽油機(jī)油的摩擦性能;納米Cu的最佳添加量為0.8%

    Abstract:

    Oil-soluble Cu nanoparticles were prepared by an oil-water interface growth method, using ascorbic acid as a reductant, polyethylene glycol (PEG-2000) as a modifier, and 1-butanol as growth agent. The particle size distribution of the obtained nanoparticles was between 18.2-80.2 nm, and the average size was 44.7 nm. The microstructures of these nanoparticles were characterized by XRD, TEM and high-concentration laser granularity scatter analyzer. The XRD patterns indicate that the lattice parameters of these Cu nanoparticles are enlarged by about 1.478%. The anti-wear and friction performance of SF15W/40 lubricating oil with these Cu nanoparticles were measured by ball-on-disk UMT-Ⅱ tribometer. It is found that the oil-soluble Cu nanoparticles have wetting effect and can be kept in dispersing form for long-term in SF15W/40 lubricating oil; the tribological performance of SF15W/40 lubricating oil with nano-Cu is improved. The best additive content of oil-soluble nano-Cu in SF15W/40 is 0.8% (mass fraction), and in such case the friction coefficient and wear loss are the lowest

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潘秋紅,張錫鳳.油溶性納米銅的制備及其在SF15W/40汽油機(jī)油中的摩擦學(xué)性能[J].稀有金屬材料與工程,2010,39(10):1711~1714.[Pan Qiuhong, Zhang Xifeng. Synthesis and Tribological Behavior of Oil-Soluble Cu Nanoparticles as Additive in SF15W/40 Lubricating Oil[J]. Rare Metal Materials and Engineering,2010,39(10):1711~1714.]
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  • 收稿日期:2009-10-11
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