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TiAl合金表面等離子噴涂MCrAlY涂層熱腐蝕行為研究
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國家自然科學(xué)基金(59975046, 50305010);江蘇省自然科學(xué)基金重點(diǎn)項(xiàng)目(BK2004005)


Study on Hot Corrosion Behavior of Plasma-Sprayed NiCoCrAl-Y2O3 Coating on TiAl Alloy Surface
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    摘要:

    研究TiAl合金表面等離子噴涂NiCoCrAl-Y2O3涂層在850 ℃下對75%Na2SO4+25%NaCl熔鹽的熱腐蝕行為,及對TiAl金屬間化合物抗高溫?zé)岣g性能的影響。研究表明,在850 ℃,等離子噴涂NiCoCrAl-Y2O3涂層由于生成Cr2O3,NiO和NiCr2O4等各種氧化物組成的氧化層,顯著提高了TiAl基體的抗熱腐蝕性能。在熱腐蝕過程中,S元素以Ni元素為載體,逐步滲入涂層中,生成過渡產(chǎn)物Ni3S2。隨著O分壓的升高,反應(yīng)進(jìn)入了氧化階段,生成Cr2O3、NiO等氧化物,隨著兩種物質(zhì)含量的增加,最后發(fā)生固相反應(yīng),生成尖晶石結(jié)構(gòu)的NiCr2O4化合物。過渡產(chǎn)物Ni3S2與腐蝕介質(zhì)中的Cl-離子形成微電池,可以加快熱腐蝕反應(yīng)速度

    Abstract:

    The hot corrosion behavior of plasma-sprayed NiCoCrAl-Y2O3 coating on TiAl alloy surface in the mixed melted salt of 75%Na2SO4+25%NaCl at 850 oC for 100 h and the influence of the coating on the anti-corrosion properties of TiAl intermetallics were investigated. The results show that the plasma-sprayed NiCoCrAl-Y2O3 coating could remarkably improve the hot corrosion resistance of TiAl matrix by generating a compound oxide layer of Cr2O3, NiO and NiCr2O4. In the course of hot corrosion, S, carried by Ni, gradually infiltrated into the composite coating and generated a transition product of Ni3S2. Then the partial pressure of the oxygen increased, followed by oxidation which produced oxides including Cr2O3 and NiO. As the amount of the both oxides increasing, the solid-state reaction took place and generated the NiCr2O4 compounds of spinel structure. The transition product of Ni3S2 and the chloridion contained in corrosion media jointly constituted micro-cell, thus accelerating hot corrosion

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田宗軍,高雪松,黃因慧,劉志東,沈理達(dá),王東生. TiAl合金表面等離子噴涂MCrAlY涂層熱腐蝕行為研究[J].稀有金屬材料與工程,2010,39(8):1439~1442.[Tian Zongjun, Gao Xuesong, Huang Yinhui, Liu Zhidong, Shen Lida, Wang Dongsheng. Study on Hot Corrosion Behavior of Plasma-Sprayed NiCoCrAl-Y2O3 Coating on TiAl Alloy Surface[J]. Rare Metal Materials and Engineering,2010,39(8):1439~1442.]
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  • 收稿日期:2009-09-28
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