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納米銀/環(huán)氧樹脂復(fù)合電介質(zhì)的電導(dǎo)特性
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Conductive Properties of Nano-Silver/Epoxy Resin Composite Dielectrics
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    摘要:

    研究了納米銀(Ag)/環(huán)氧樹脂(EP)復(fù)合材料的直流體積電阻率和強場電導(dǎo)。結(jié)果表明,在環(huán)氧樹脂中微量添加小尺寸的銀納米粒子后,復(fù)合材料的體積電阻率比純環(huán)氧樹脂有明顯提高,并且電阻率的增加與銀粒子尺寸、含量,以及基體聚合物的特性有關(guān)。對復(fù)合材料強場電導(dǎo)的研究表明,小尺寸的銀粒子在聚合物中分散良好時,復(fù)合物的強場電導(dǎo)表現(xiàn)出庫侖阻塞特性,即納米粒子可限制載流子的遷移。而當(dāng)納米粒子的粒徑過大或添加較多時,復(fù)合材料在強電場下表現(xiàn)出對電荷的捕獲與脫陷,具有明顯的空間電荷限制電流特性。熱刺激電流特性反映出納米粒子與聚合物在界面處形成深陷阱是產(chǎn)生空間電荷限制電流的原因

    Abstract:

    The DC volume resistivity and high field conductivity of nano-Ag/epoxy resin polymer composite were researched. The results show after trace addition of Ag nanoparticles with small sizes, the composite has obviously higher volume resistivity than pure epoxy resin. The increase of resistivity is relative with Ag particle size, adding content and characteristics of base polymer. High field conductivity tests show that the coulomb blockade effect appears when Ag particles of small size disperse evenly in the polymer, i.e. the transmission of electron charge can be restricted by nanoparticles. When the adding content of Ag nanoparticles is too much or their size is too big, the composite shows space charge limited current property. TSC results show that more deep traps exist at the interface between nano Ag and polymer, which causes space charge limited current for charge captured and escaped from the traps

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徐 曼,曹曉瓏.納米銀/環(huán)氧樹脂復(fù)合電介質(zhì)的電導(dǎo)特性[J].稀有金屬材料與工程,2010,39(8):1370~1374.[Xu Man, Cao Xiaolong. Conductive Properties of Nano-Silver/Epoxy Resin Composite Dielectrics[J]. Rare Metal Materials and Engineering,2010,39(8):1370~1374.]
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  • 收稿日期:2009-10-28
  • 最后修改日期:2010-06-02
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