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Ni-Co-Cr高溫合金中3d電子及鍵結構的正電子湮沒研究
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國家自然科學基金項目(50361002);江蘇省普通高校自然科學研究計劃資助項目(07KJD430041)和江蘇技術師范學院青年科研基金項目(KYY06094)資助


Study on 3d-Shell Electrons and Bond Configuration in Ni-Co-Cr Superalloys by Positron Annihilation Spectroscopy
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    摘要:

    利用雙探頭符合系統(tǒng),測量純金屬Ni、Co、Cr以及3種不同成分的Ni-Co-Cr合金的正電子湮沒輻射Doppler展寬譜,分析形成Ni-Co-Cr合金時3d電子的作用。結果表明,3種純金屬中Ni的3d電子信號較強,當增加Ni-Co-Cr合金中的Ni原子的比例時,導致正電子與自由電子湮沒的幾率增加。不同成分Ni-Co-Cr合金的實驗商譜與其合成商譜保持了較好的一致性,這顯示出在Ni-Co-Cr合金中不同原子之間主要以金屬鍵相結合,這可能是Ni-Co-Cr合金具有較好金屬延展性的原因之一。

    Abstract:

    Doppler-broadening spectra of positron annihilation radiation for pure metals Ni, Co and Cr and Ni-Co-Cr alloys with three different chemical compositions were measured by 2-detector coincidence technique. And the effect of the 3d electrons on Ni-Co-Cr alloy formation was analyzed. The results show that the 3d electron signal for the metal Ni is relatively higher among the three pure metals. The increase of Ni atom proportion in Ni-Co-Cr alloys leads to an increase in the probability of positron annihilation with free electrons. The experimental ratio curves for three Ni-Co-Cr alloys are greatly similar to the corresponding theoretic ratio curves, which indicate that the bonding nature in Ni-Co-Cr alloys is mainly metallic. This can explain why the Ni-Co-Cr alloys have good metal ductility.

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胡益豐,郝文博,鄧 文. Ni-Co-Cr高溫合金中3d電子及鍵結構的正電子湮沒研究[J].稀有金屬材料與工程,2010,39(7):1171~1174.[Hu Yifeng, Hao Wenbo, Deng Wen. Study on 3d-Shell Electrons and Bond Configuration in Ni-Co-Cr Superalloys by Positron Annihilation Spectroscopy[J]. Rare Metal Materials and Engineering,2010,39(7):1171~1174.]
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  • 收稿日期:2009-08-15
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