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中溫SOFC復(fù)合陰極材料的制備及性能
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Preparation and Performance of Composite Cathode Materials for IT-SOFC
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    摘要:

    在La0.7Sr0.3Co0.95Cu0.05O3-δ中摻入不同比例的Ce0.8Sm0.2O1.9制成中溫固體氧化物燃料電池(IT-SOFC)復(fù)合陰極材料,對(duì)其進(jìn)行晶體結(jié)構(gòu)表征和高溫電導(dǎo)率、熱膨脹系數(shù)和陰極過(guò)電位測(cè)試。結(jié)果表明,Ce0.8Sm0.2O1.9的摻入不但有效地降低了La0.7Sr0.3Co0.95Cu0.05O3-δ陰極材料的熱膨脹系數(shù),而且Ce0.8Sm0.2O1.9摻入量為10%(質(zhì)量分?jǐn)?shù),下同)的樣品,其電導(dǎo)率高于La0.7Sr0.3Co0.95Cu0.05O3-δ,并且它在相同過(guò)電位下其陰極電流密度也大于其他樣品。以其為陰極的SOFC單電池,在850 ℃最大短路電流密度達(dá)511 mA/cm2,最大輸出功率密度為106 mW/cm2。

    Abstract:

    A composite cathode material for Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFC) was prepared by adding Ce0.8Sm0.2O1.9 into La0.7Sr0.3Co0.95Cu0.05O3-δ at different ratios. The crystal structure was characterized; the high temperature conductivity, thermal expansion coefficient and overpotentials of cathode electrodes were tested. The results show that adding Ce0.8Sm0.2O1.9 effectively decreases the thermal expansion coefficient of La0.7Sr0.3Co0.95Cu0.05O3-δ. When the content of the adding of Ce0.8Sm0.2O1.9 is 10% (mass faction, similarly hereinafter), the conductivity of the composite material is higher than that of La0.7Sr0.3Co0.95Cu0.05O3-δ and the current density of the cathode under the same overpotential is greater than that of others. A single fuel cell containing this cathode material has the maximum short-circuit current density of 511 mA/cm-2 and the maximum output power density of 106 mW /cm-2 at 850 °C.

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荊 波,孫俊才,呂 喆.中溫SOFC復(fù)合陰極材料的制備及性能[J].稀有金屬材料與工程,2010,39(5):915~918.[Jing Bo, Sun Juncai, Lü Zhe. Preparation and Performance of Composite Cathode Materials for IT-SOFC[J]. Rare Metal Materials and Engineering,2010,39(5):915~918.]
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  • 收稿日期:2009-05-20
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