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預(yù)處理工藝對(duì)放電等離子燒結(jié)超細(xì)晶WC-Co硬質(zhì)合金組織和性能的影響
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國家自然科學(xué)基金(50671001, 50871001);教育部新世紀(jì)優(yōu)秀人才項(xiàng)目(NCET2006);教育部博士點(diǎn)基金(20070005010);北京特色新材料產(chǎn)業(yè)關(guān)鍵技術(shù)研發(fā)攻關(guān)類項(xiàng)目(Z08000003220000)


Effect of Pretreatment on Microstructure and Properties of Ultrafine WC-Co Cermets by Spark Plasma Sintering
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    摘要:

    采用不同粒度的WC粉與超細(xì)Co粉混合得到初始粉末,利用直接放電等離子燒結(jié)(SPS)技術(shù)和一種包括真空預(yù)處理和SPS燒結(jié)的新制備方法,研制超細(xì)晶WC-Co硬質(zhì)合金塊體。結(jié)果表明,兩種不同粒度匹配的混合粉末經(jīng)真空預(yù)處理后SPS燒結(jié)得到的試樣較直接SPS燒結(jié)試樣的硬度稍有降低,但斷裂韌性得到提高,尤其是抗拉強(qiáng)度得到顯著提高。對(duì)試樣顯微組織和性能分析表明,混合粉末的真空預(yù)處理工藝對(duì)SPS燒結(jié)WC-Co硬質(zhì)合金具有重要作用:去除混合粉末吸附氣體,消除Co池,同時(shí)保證WC晶粒不發(fā)生明顯長(zhǎng)大。

    Abstract:

    WC powders with different particle sizes and ultrafine Co powders were mixed to form the initial powders. Afterwards ultrafine WC-Co cermet bulks were prepared by direct SPS and a new method combining vacuum pretreatment with SPS. Results show that the samples prepared by pretreatment and SPS have a little lower hardness but higher fracture toughness and much higher tensile strength than those by direct SPS. The analyses of microstructures and properties indicate that the vacuum pretreatment has important effect on the WC-Co cermets by SPS. It can release the adsorbed gas, cancel the “Co lake” and obtain completely densified bulks without significant grain growth.

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趙世賢,宋曉艷,王明勝,魏崇斌,劉雪梅,張久興.預(yù)處理工藝對(duì)放電等離子燒結(jié)超細(xì)晶WC-Co硬質(zhì)合金組織和性能的影響[J].稀有金屬材料與工程,2010,39(5):896~901.[Zhao Shixian, Song Xiaoyan, Wang Mingsheng, Wei Chongbin, Liu Xuemei, Zhang Jiuxing. Effect of Pretreatment on Microstructure and Properties of Ultrafine WC-Co Cermets by Spark Plasma Sintering[J]. Rare Metal Materials and Engineering,2010,39(5):896~901.]
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  • 收稿日期:2009-05-10
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