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制備條件對Au/AC催化分解臭氧性能的影響
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國家“863”計劃(2006AA06Z377);國家自然科學基金(50772058);國家重點實驗室專項基金(08Y02ESPCT)


Influence of Preparation Conditions on Catalytic Activity of Au/AC for Ozone Decomposition
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    摘要:

    研究了活性炭負載的金催化劑(Au/AC)對低濃度臭氧的催化分解性能,考察了前驅體溶液pH值、干燥方式、焙燒溫度等制備條件對催化劑活性的影響,以及空速對臭氧分解率的影響。結果表明,在金前驅體溶液pH值為10、經(jīng)微波輻射干燥、200 ℃氫氣還原制備的催化劑,金顆粒在活性炭表面的分布更加均勻,尺寸更小,具有更高的催化活性。在室溫、相對濕度45%和空速72 000 h-1時,對濃度為50 mg/m3臭氧的分解率保持在90%以上(在2400 min內)。N2吸附-脫附和XPS表征結果表明,活性炭載金催化劑在催化分解臭氧后,比表面積和孔體積略有下降;Au4f的XPS峰雖稍向高能方向移動,但仍保持催化活性;活性炭表面碳含量顯著下降而氧含量大幅增加,說明活性炭上負載的Au在自身催化分解臭氧的同時,還起到了促進臭氧與單質碳反應的作用

    Abstract:

    The activity of Au catalyst supported by activated carbon (Au/AC) for decomposition of low-level ozone was evaluated. The influence of preparation conditions such as pH value of precursor solution, drying mode and calcining temperature on the catalytic activity was studied, and the ozone removal ratio was tested under different space velocity at ambient temperature. The results show that the procedure of controlling the precursor pH=10, drying catalysts by microwave and being reduced at 200℃ with H2 can improve the dispersion of gold particle, decrease particle sizes and significantly enhance the activity of Au/AC for ozone decomposition. When the catalytic activity test was carried out under the condition of 50 mg/m3 ozone in air, relative humidity 45%, space velocity 72 000 h-1 and ambient temperature, the ozone removal ratio could be maintained above 90% (within 2400 min). The results of N2 adsorption-desorption and XPS show that, after the reaction with ozone the specific surface area and pore volume of Au/AC decrease slightly; Au/AC remains active although the spectrum peaks of Au4f shift toward higher. Furthermore, the fact that C content decreased notably while O increased, reveals that the Au supported on AC is concerned with the catalytic reaction and can concurrently promote another reaction between ozone and graphitic C

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張 博,史 蕊,張彭義,徐九華.制備條件對Au/AC催化分解臭氧性能的影響[J].稀有金屬材料與工程,2010,39(4):692~696.[Zhang Bo, Shi Rui, Zhang Pengyi, Xu Jiuhua. Influence of Preparation Conditions on Catalytic Activity of Au/AC for Ozone Decomposition[J]. Rare Metal Materials and Engineering,2010,39(4):692~696.]
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  • 收稿日期:2009-04-27
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