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鉑含量對改性鋁化物粘結(jié)層高溫氧化和內(nèi)應(yīng)力的影響
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Effect of Pt Content on High Temperature Oxidation and Residual Stress of Pt-Modified Aluminide Bondcoatings
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    研究鎳基高溫合金的熱障涂層系統(tǒng)中不同鉑含量的改性鋁化物粘結(jié)層在1100 ℃空氣中循環(huán)氧化和非連續(xù)氧化行為及生成的氧化鋁層的內(nèi)應(yīng)力狀態(tài)。發(fā)現(xiàn)在不同循環(huán)氧化條件下,鉑鋁粘結(jié)層表面都形成連續(xù)致密的α-Al2O3層,并且α-Al2O3具有相同的形態(tài)和相似的平均厚度。而在非連續(xù)氧化初期,Al2O3層熱生長應(yīng)力快速增大,在氧化至100 h時內(nèi)應(yīng)力出現(xiàn)峰值。同時由于高含量鉑促進(jìn)Al元素的擴散從而改變了涂層力學(xué)性能,造成高含量鉑涂層中表現(xiàn)較大的內(nèi)應(yīng)力,但鉑含量不能影響Al2O3層中內(nèi)應(yīng)力曲線變化趨勢。另外,低鉑含量涂層γ′-Ni3Al多沿β-NiAl晶界生成,而高含量鉑使涂層晶粒細(xì)化,導(dǎo)致γ′-Ni3Al相呈彌散分布生長,從而可以形成Al元素的“網(wǎng)”狀快速擴散通道

    Abstract:

    Cyclic and discontinuous high-temperature oxidation behavior and the residual stress of thermal growth oxide (TGO) of modified aluminide bond coating with different Pt contents in nickel base superalloys for TBC (thermal barrier coating) application were studied in air at 1100 °C. It was found that the continuous and compact α-Al2O3 layers formed over Pt modified aluminide bond coating in the process of the cyclic oxidation, and the two Pt-modified aluminide coatings with different Pt contents had similar morphology and thickness. Thermal growth stress of α-Al2O3 layers increased quickly during initial discontinuous oxidation and a peak value of the residual stress appeared when the coating oxidation was prolonged to 100 h; at the same time, the high content of Pt promoted the diffusion of element Al, resulting in changing the mechanical property of the coating, and exhibiting a relatively great residual stress in the coating with high content of Pt, but the high content of Pt had no influence upon the change trend of the residual stress curve of α-Al2O3 layers. In addition, γ′-Ni3Al phase usually grew along β-NiAl grain boundary, while the high content of Pt would refine coating grains, resulting in γ′-Ni3Al growth in the way of dispersion distribution, and thus a net-like high velocity diffusion channel for element Al would form

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宋 鵬,陸建生,呂建國,張德豐.鉑含量對改性鋁化物粘結(jié)層高溫氧化和內(nèi)應(yīng)力的影響[J].稀有金屬材料與工程,2010,39(4):613~617.[Song Peng, Lu Jiansheng, Lü Jianguo, Zhang Defeng. Effect of Pt Content on High Temperature Oxidation and Residual Stress of Pt-Modified Aluminide Bondcoatings[J]. Rare Metal Materials and Engineering,2010,39(4):613~617.]
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  • 收稿日期:2009-04-28
  • 最后修改日期:2010-02-03
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