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A2W3O12(A=Y, Er, Ho, Yb)型稀土鎢酸鹽的高溫XRD研究及結構精修
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深圳大學科研啟動基金(200827)


High-Temperature XRD Study and Rietveld Refinement of A2W3O12(A=Y, Er, Ho, Yb) Rare-Earth Tungstate
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    摘要:

    用高溫固相反應法制備出A2W3O12 型稀土鎢酸鹽材料(A=Y,Er,Ho,Yb),用室溫及高溫XRD測定其在不同溫度下的結構、晶胞參數(shù)及晶胞體積,并用TOPSA軟件對其結構進行精修。發(fā)現(xiàn)除Ho2W3O12外,都具有較大的負熱膨脹系數(shù)。據(jù)A. W. Sleight預測,Ho2W3O12具有較大的負熱膨脹特性,但本實驗卻發(fā)現(xiàn)它并沒有負熱膨脹性,反而具有非常大的正熱膨脹系數(shù)。

    Abstract:

    A2W3O12(A=Y, Er, Ho, Yb) rare-earth tungstate materials were synthesized by solid state method at high temperature. The structures, lattice constants and cell volumes of A2W3O12 were determined by room temperature and high temperature XRD at different temperatures, and their Rietveld refinements were performed by TOPAS software. It is found that Y2W3O12, Er2W3O12 and Yb2W3O12 all possess orthorhombic structure and show negative thermal expansion; whereas Ho2W3O12 has monoclinic structure and shows positive thermal expansion. According to A. W. Sleight prediction, Ho2W3O12 should have large negative thermal expansion, but it shows no negative thermal expansion but large positive thermal expansion coefficient in the present experiment.

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黃遠輝,楊海濤,尚福亮,吳國根,汪 曉. A2W3O12(A=Y, Er, Ho, Yb)型稀土鎢酸鹽的高溫XRD研究及結構精修[J].稀有金屬材料與工程,2009,38(12):2131~2135.[Huang Yuanhui, Yang Haitao, Shang Fuliang, Wu Guogen, Wang Xiao. High-Temperature XRD Study and Rietveld Refinement of A2W3O12(A=Y, Er, Ho, Yb) Rare-Earth Tungstate[J]. Rare Metal Materials and Engineering,2009,38(12):2131~2135.]
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  • 收稿日期:2008-12-08
  • 最后修改日期:2009-11-27
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