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輥速及晶化工藝對(Nd, Pr)13Fe80Nb1B6快淬薄帶組織和矯頑力的影響
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國家重大基礎(chǔ)研究前期專項(2004CCA04000);國家自然科學(xué)基金(50744014);浙江省科技計劃重點項目(2008C21046); 浙江省自然科學(xué)基金(Y406389);江西省重要學(xué)科跨世紀學(xué)術(shù)和技術(shù)帶頭人培養(yǎng)計劃資助項目(CA99110901); 寧波市科技攻關(guān)項目(2006B100054); 寧波大學(xué)王寬誠幸?;?/p>


Effects of Wheel Velocity and Subsequent Crystallization on the Microstructures
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    摘要:

    用熔體快淬法制備(Nd,Pr)13Fe80Nb1B6快淬薄帶并晶化處理,研究輥速和晶化條件對其組織和矯頑力的影響。結(jié)果表明,在10~20、25和35 m/s分別得到納米晶、部分非晶和完全非晶薄帶,且在18 m/s制備的薄帶有較好的c軸各向異性。快淬態(tài)薄帶的矯頑力隨輥速(10~25 m/s)的增大而增加。非晶薄帶晶化后由(Nd,Pr)2Fe14B相和富稀土相組成,且完全非晶薄帶晶化后比部分非晶薄帶晶化后的矯頑力要高,這是由于前者比后者具有更均勻的微結(jié)構(gòu)造成的。非晶薄帶晶化后矯頑力最大為1616 kA/m,高的矯頑力與添加Pr和Nb有關(guān)

    Abstract:

    (Nd,Pr)13Fe80Nb1B6 ribbons were melt-spun at 10~35 m/s and subsequently crystallized, the effect of wheel velocity and crystallization conditions on the microstructures and coercivities were studied. The XRD results indicate that the ribbons spun at 10~20 m/s consist of (Nd, Pr)2Fe14B nano-crystalline phase, while the ribbons spun at 25 and 35 m/s are partly and fully amorphous, respectively. In addition, the (004), (006) and (008) peaks of (Nd, Pr)2Fe14B are obvious on the ribbons spun at 18 m/s, suggesting the c-axis anisotropy. The coercivity of the ribbons prepared at 10~25 m/s increases with the increase of wheel velocity, with the maximum of 1216 kA/m at 25 m/s. After the ribbons spun at 25 m/s and 35 m/s are crystallized, the (Nd, Pr)2Fe14B phase and rich-rare earth phase are co-existed. And the coercivities of the ribbons spun at 35 m/s are much higher and with more homogeneous microstructures than those at 25 m/s. The maximum coercivity, 1616 kA/m, is obtained in the ribbons spun at 35 m/s after crystallizing at 973 K for 19 min due to the Pr and Nb addition. Because the Pr2Fe14B has a higher anisotropic coercive field than that of Nd2Fe14B, and the Nb element can inhibit the formation of α-Fe phase and refine the sizes of grains

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劉新才,郭鵬舉,潘 晶,徐 峰,李 勇,崔 平.輥速及晶化工藝對(Nd, Pr)13Fe80Nb1B6快淬薄帶組織和矯頑力的影響[J].稀有金屬材料與工程,2009,38(11):2027~2031.[Liu Xincai, Guo Pengju, Pan Jing, Xu Feng, Li Yong, Cui Ping. Effects of Wheel Velocity and Subsequent Crystallization on the Microstructures[J]. Rare Metal Materials and Engineering,2009,38(11):2027~2031.]
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  • 收稿日期:2008-12-15
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