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納米復合材料CdS/TiO2NTs的制備及光催化產氫活性
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Preparation of CdS/TiO2NTs Nanocomposite and Its Activity of Photocatalytic Hydrogen Production
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Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) (20050698034); Natural Science Basic Research Plan in Shaanxi Province of China (SJ08E106)

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    摘要:

    通過離子交換和沉淀反應制備納米復合材料CdS/TiO2NTs。采用X射線衍射(XRD)、掃描電鏡(SEM)、透射電鏡(TEM)、漫反射紫外-可見吸收光譜(DRUVAS)、熒光光譜(FES)、X射線熒光分析(XRF)等手段對該復合材料的結構進行表征。SEM結果表明:鈦酸鹽納米管的形成經由TiO2顆粒-片狀的鈦酸鹽-卷曲的鈦酸鹽納米管的自組裝過程。XRD、DRUVAS、FES和FES結果表明:平均粒度大約 8 nm 的六方相CdS均勻的負載于銳鈦礦型TiO2納米管表面,其吸收邊擴展到可見區(qū)。與TiO2納米管及TiO2粉末相比,CdS/TiO2NTs 納米復合材料展示了較高的可見光催化分解水產氫活性

    Abstract:

    The CdS/TiO2NTs nanocomposite was prepared through ion-exchange and precipitation reactions. The nanostructure properties of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse reflectance UV-visible absorption spectra (DRUVAS), fluorescence emission spectra (FES) and X-ray fluorescence analyzer (XRF). SEM results revealed that the lamellar sodium trititanate originating from the TiO2 particles individually curled to form the sodium trititanate nanotubes by self-assembled mechanism. The results of XRD, TEM and DRUVAS demonstrated that hexagonal phase CdS with about 8 nm particle size were homogeneously loaded on the surface of anatase TiO2NTs and the absorption edge of the composite was extended to the visible region. The CdS/TiO2NTs composite exhibited the highest activity of hydrogen production (1708 mL/g) by photocatalytic water decomposition in comparison with TiO2NTs and TiO2 powder under visible light irradiation (l > 400 nm) for 6 h

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張耀君,吳言沛,王振華,胡亞茹.納米復合材料CdS/TiO2NTs的制備及光催化產氫活性[J].稀有金屬材料與工程,2009,38(9):1514~1517.[Zhang Yaojun, Wu Yanpei, Wang Zhenhua, Hu Yaru. Preparation of CdS/TiO2NTs Nanocomposite and Its Activity of Photocatalytic Hydrogen Production[J]. Rare Metal Materials and Engineering,2009,38(9):1514~1517.]
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  • 收稿日期:2008-09-15
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