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Nd3+對燒結(jié)Nd-Fe-B化學(xué)鍍Ni-P合金結(jié)合力和耐蝕性的影響
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國家自然科學(xué)基金項目(50701039), 新世紀(jì)優(yōu)秀人才支持計劃(05-0526), 教育部創(chuàng)新團(tuán)隊發(fā)展計劃(IRT-0651)資助


Effects of Nd3+ on Adhesion And Corrosion Resistance of Electroless Ni-P Coating on Sintered Nd-Fe-B Magnets
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    摘要:

    在化學(xué)鍍液中添加Nd3+,研究其濃度對Ni-P鍍層與燒結(jié)Nd-Fe-B磁體的結(jié)合力和施鍍后磁體耐蝕性的影響。測定添加不同濃度Nd3+鍍液中所得Ni-P鍍層與磁體的結(jié)合力,以及鍍層在3.5% NaCl(質(zhì)量分?jǐn)?shù),下同)溶液中的極化曲線,并結(jié)合中性鹽霧實驗表征施鍍后磁體耐蝕性。結(jié)果表明,添加2.5 g·L-1 Nd3+時,Ni-P鍍層與Nd-Fe-B磁體的結(jié)合力從6.4 MPa提高至25.2 MPa;施鍍后磁體的自腐蝕電位從–0.382 V升高到–0.148 V,自腐蝕電流密度從4.52 μA·cm-2降低到

    Abstract:

    Ni-P coatings were deposited on sintered Nd-Fe-B magnets through the addition of Nd3+ in the electroless plating solution. The effects of Nd3+ concentration on the adhesion and corrosion resistance of the coatings were investigated. The adhesions between the magnets and the Ni-P coatings were measured in different Nd+ concentration plating solutions, and the polarization curves of the coatings in 3.5% (mass fraction) NaCl solution were plotted, the magnet corrosion resistances were characterized by neutral salt spray experiment. The results showed that the addition of Nd3+ could significantly improve the adhesion and corrosion resistance of Ni-P coatings on magnets. When increasing Nd3+ up to 2.5 g·L-1, the adhesion strength of the Ni-P coating to Nd-Fe-B magnet was enhanced from 6.4 to 25.2 MPa. Synchronously, the corrosion potential Ecorr of the coated magnets in 3.5% NaCl solution increased from -0.382 to -0.148 V, the corrosion current density Icorr decreased from 4.52 to 0.07 μA·cm-2, and the coated magnets could be as long as 256 h free of corrosion in the neutral salt spray, reflecting the improvement of corrosion resistance.

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吳元騄,羅 偉,嚴(yán) 密. Nd3+對燒結(jié)Nd-Fe-B化學(xué)鍍Ni-P合金結(jié)合力和耐蝕性的影響[J].稀有金屬材料與工程,2009,38(6):1096~1099.[Wu Yuanlu, Luo Wei, Yan Mi. Effects of Nd3+ on Adhesion And Corrosion Resistance of Electroless Ni-P Coating on Sintered Nd-Fe-B Magnets[J]. Rare Metal Materials and Engineering,2009,38(6):1096~1099.]
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  • 收稿日期:2008-06-23
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