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Ni微網(wǎng)格透明電極的制備及透光性能研究
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國家自然科學(xué)基金項(xiàng)目(50732004)


Preparation of Ni Microgrid Transparent Electrode and Its Transmission Property
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    摘要:

    以聚苯乙烯膠體晶體為模板,采用磁控濺射方法制備了孔徑分別為1.2,2.4,3.4,4.5和5.6 μm的Ni微網(wǎng)格透明電極。利用掃描電子顯微鏡(SEM)、紫外可見分光光度計(jì)(UV-Vis)和四探針測試儀考察了微網(wǎng)格孔徑對電極透過率及導(dǎo)電性能的影響。發(fā)現(xiàn)隨網(wǎng)格孔徑增大,電極透過率逐漸降低,導(dǎo)電性能逐漸增強(qiáng)。微網(wǎng)格透明電極在紫外與可見光區(qū)具備優(yōu)良的透明導(dǎo)電性能。微網(wǎng)格結(jié)構(gòu)的理論計(jì)算和原子力顯微鏡(AFM)分析結(jié)果表明,隨著模板中PS球直徑的增大,Ni在基底上覆蓋厚度的線性增大,是導(dǎo)致微網(wǎng)格透明電極透光性能下降

    Abstract:

    Ni microgrid transparent electrodes with different pore sizes (1.2,2.4,3.4,4.5 and 5.6 μm), were prepared via sputtering Ni into the gaps of PS colloidal crystal templates by magnetron sputtering. The influence of the pore sizes on the transmittance and the electric properties of the Ni microgrid transparent electrodes were investigated by SEM, UV-Vis spectrometer and four-point probe. It was found that the transmittance decreased and electric properties increased with the increase of the pore sizes of the samples. Ni microgrid transparent electrode showed a low electrical resistance and high transmittance in the ultraviolet-visible range. The results of theoretical calculation and AFM analysis indicated that the height of microgrid increased with the increase of the diameter of PS particles, which is the fundamental reason for the decrease of the transmission properties and the increase of electric properties of Ni microgrid transparent electrodes.

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祁洪飛,郝維昌,王天民. Ni微網(wǎng)格透明電極的制備及透光性能研究[J].稀有金屬材料與工程,2009,38(6):1080~1083.[Qi Hongfei, Hao Weichang, Wang Tianmin. Preparation of Ni Microgrid Transparent Electrode and Its Transmission Property[J]. Rare Metal Materials and Engineering,2009,38(6):1080~1083.]
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  • 收稿日期:2008-06-22
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